4 Synthesis of Carbocation Salts of Boron Cluster Anions [B10H10]2- and [B12H12]2-

被引：5

作者：

Zhdanov, A. P. ^{[1
]}

Retivov, V. M. ^{[2
]}

Razgonyaeva, G. A. ^{[1
]}

Zhizhin, K. Yu. ^{[1
]}

Kuznetsov, N. T. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 117907, Russia

[2] Res Inst Highly Pure Chem Subst & Chem, Moscow 107076, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2015年 / 60卷 / 07期

基金：

俄罗斯基础研究基金会;

关键词：

CLOSO-DECABORATE; POLYMERIC PRECURSORS; CHEMISTRY; BORANES; B10H10-2; CERAMICS; B12H12-2;

D O I：

10.1134/S0036023615070189

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of closo-decaborates and closo-dodecaborates as carbocation salts was obtained by the reaction of Kat(2)[BnHn] (n = 10, 12; Kat = Na, K, Ag) with tertiary alkyl halides (C4H9Cl)-C-t, 1-AdBr, and (C6H5)(3)CCl. The prepared compounds were identified by IR and H-1, B-11, C-13 NMR spectroscopy.

引用

页码：771 / 775

页数：5

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