Solubility Product of MoC with NaCl Type Cubic Crystal Structure in Iron

被引:5
作者
Cao, Jianchun [1 ]
Zhou, Xiaolong [1 ]
Deng, Lei [1 ]
Yong, Qilong [2 ]
Sun, Xinjun [2 ]
Liu, Qingyou [2 ]
机构
[1] Kunming Univ Sci & Technol, Sch Mat Sci & Engn, Kunming 650093, Yunnan, Peoples R China
[2] Inst Struct Mat, Cent Iron & Steel Res Inst, Beijing 100081, Peoples R China
来源
NEW MATERIALS AND PROCESSES, PTS 1-3 | 2012年 / 476-478卷
基金
国家高技术研究发展计划(863计划);
关键词
MoC; Cubic Crystal Structure; Solubility Product; Ferrite; Austenite; HIGH-STRENGTH; STEELS; NB; PRECIPITATION; MICROSTRUCTURE; THERMODYNAMICS; ALLOYS;
D O I
10.4028/www.scientific.net/AMR.476-478.281
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this paper, firstly, the equilibrium solubility product formula of MoC with NaCl type cubic crystal structure in ferrite has been deduced by thermodynamic method, according to the free energy change of molybdenum and carbon dissolved in ferrite and the formation energy of MoC. On the basis of deducing activity coefficients of Mo in iron, the solubility product formula of MoC in austenite has been obtained according to the relationship of solubility product of MoC in austenite and ferrite. Finally, the solubility products for MoC and NbC in iron are compared. The solubility product formulae of MoC deduced would play an important role in related theoretical research and practical production.
引用
收藏
页码:281 / +
页数:2
相关论文
共 16 条
[1]   A THERMODYNAMIC EVALUATION OF THE FE-MO-C SYSTEM [J].
ANDERSSON, JO .
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 1988, 12 (01) :9-23
[2]   THERMODYNAMICS OF AUSTENITIC FE-C ALLOYS [J].
BANYA, S ;
ELLIOTT, JF ;
CHIPMAN, J .
METALLURGICAL TRANSACTIONS, 1970, 1 (05) :1313-&
[3]   Precipitation of MC phase and precipitation strengthening in hot rolled Nb-Mo and Nb-Ti steels [J].
Cao, Jianchun ;
Yong, Qilong ;
Liu, Qingyou ;
Sun, Xinjun .
JOURNAL OF MATERIALS SCIENCE, 2007, 42 (24) :10080-10084
[4]  
Hao Shiming, 2004, MAT THERMODYNAMIC
[5]  
Jianchun Cao, 2005, CHINA MOLYBDENUM IND, V29, P46
[6]   Influence of Mo content on microstructure and mechanical properties of high strength pipeline steel [J].
Kong, JH ;
Zhen, L ;
Guo, B ;
Li, PH ;
Wang, AH ;
Xie, CS .
MATERIALS & DESIGN, 2004, 25 (08) :723-728
[7]   Influence of Mo on precipitation hardening in hot rolled HSLA steels containing Nb [J].
Lee, WB ;
Hong, SG ;
Park, CG ;
Kim, KH ;
Park, SH .
SCRIPTA MATERIALIA, 2000, 43 (04) :319-324
[8]   Carbide precipitation and high-temperature strength of hot-rolled high-strength, low-alloy steels containing Nb and Mo [J].
Lee, WB ;
Hong, SG ;
Park, CG ;
Park, SH .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2002, 33 (06) :1689-1698
[9]   THERMODYNAMICS AND SOLUBILITY OF CARBON IN FERRITE AND FERRITIC FE-MO ALLOYS [J].
LOBO, JA ;
GEIGER, GH .
METALLURGICAL TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 1976, 7 (09) :1347-1357
[10]   Quantitative analysis of complex carbo-nitride precipitates in steels [J].
Scott, CP ;
Chaleix, D ;
Barges, P ;
Rebischung, V .
SCRIPTA MATERIALIA, 2002, 47 (12) :845-849