Independent Control of Optical and Explosive Properties: Pyrazole-Tetrazine Complexes of First Row Transition Metals

被引：22

作者：

Myers, Thomas W. ^{[1
]}

Chavez, David E. ^{[1
]}

Hanson, Susan K. ^{[2
]}

Scharff, R. Jason ^{[1
]}

Scott, Brian L. ^{[3
]}

Veauthier, Jacqueline M. ^{[2
]}

Wu, Ruilian ^{[4
]}

机构：

[1] Los Alamos Natl Lab, M Div, Los Alamos, NM 87545 USA

[2] Los Alamos Natl Lab, Div Chem, Los Alamos, NM 87545 USA

[3] Los Alamos Natl Lab, Mat Phys & Applicat, Los Alamos, NM 87545 USA

[4] Los Alamos Natl Lab, Biosci Div, Los Alamos, NM 87545 USA

来源：

INORGANIC CHEMISTRY | 2015年 / 54卷 / 16期

关键词：

NITROGEN-RICH; LIGAND; COPPER; DECOMPOSITION; PERCHLORATE; COMBUSTION; ABSORPTION; INITIATION; CHEMISTRY; NITRATE;

D O I：

10.1021/acs.inorgchem.5b01313

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes of 3-amino-6-(3,5-dimethylpyrazole)-tetrazine) (NH(2)TzDMP, 1) and 3-(3,3'-dinitroazetidine)-6-(3,5-dimethylpyrazole)tetrazine) (DNAZTzDMP, 2) with first row transition metal centers were synthesized. Reactions of Fe-II(H2O)(6)(BF4)(2) and Fe(NO3)(3)center dot 9H(2)O with 1 and 2 both led to complexes of the form [(RTzDMP)(3)Fe]X-2 (X = BF4, R = NH2 (3), DNAZ (4); X = NO3, R = NH2 (5), DNAZ (6)), which showed intense MLCT bands in the visible region of the spectrum. Ligands 1 and 2 also reacted with Cu-II(NO3)(2)center dot 5/2H(2)O to form [(RTzDMP)(2)Cu(NO3)][NO3] (R = NH2 (7), DNAZ (8)) in addition to reacting with Cu-I(CH3CN)(4)(PF6) to form [(RTzDMP)(2)Cu][PF6] (R = NH2 (9), DNAZ (10)). Lastly reactions of 1 and 2 with Co(NO3)(2)center dot 6H(2)O and Ni(NO3)(2)center dot 6H(2)O led to [(NH(2)TzDMP)(2)Co(H2O) (NO3)] [NO3] (11), [(DNAZTzDMP)(2)Co(H2O)(2)] [NO3](2) (12), [(NH(2)TzDMP)(3)Ni][NO3](2) (13), and [(DNAZTzDMP)(2)Ni(H2O)(2)[NO3](2) (14). The complexes display rich electrochemical and photophysical properties that are unaffected by derivation with explosive groups.

引用

页码：8077 / 8086

页数：10

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