共 44 条
Selective detection of dopamine based on Cu2O@ Pt core-shell nanoparticles modified electrode in the presence of ascorbic acid and uric acid
被引:39
作者:

Jin, Jiayi
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Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Wuhan 430062, Peoples R China
Hubei Univ, Key Lab Synth & Applicat Organ Funct Mol, Minist Educ, Wuhan 430062, Peoples R China
Hubei Univ, Coll Chem & Chem Engn, Wuhan 430062, Peoples R China Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Wuhan 430062, Peoples R China

Mei, He
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Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Wuhan 430062, Peoples R China
Hubei Univ, Key Lab Synth & Applicat Organ Funct Mol, Minist Educ, Wuhan 430062, Peoples R China
Hubei Univ, Coll Chem & Chem Engn, Wuhan 430062, Peoples R China Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Wuhan 430062, Peoples R China

Wu, Huimin
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Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Wuhan 430062, Peoples R China
Hubei Univ, Key Lab Synth & Applicat Organ Funct Mol, Minist Educ, Wuhan 430062, Peoples R China
Hubei Univ, Coll Chem & Chem Engn, Wuhan 430062, Peoples R China Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Wuhan 430062, Peoples R China

Wang, Shengfu
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Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Wuhan 430062, Peoples R China
Hubei Univ, Key Lab Synth & Applicat Organ Funct Mol, Minist Educ, Wuhan 430062, Peoples R China
Hubei Univ, Coll Chem & Chem Engn, Wuhan 430062, Peoples R China Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Wuhan 430062, Peoples R China

Xia, Qinghua
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h-index: 0
机构:
Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Wuhan 430062, Peoples R China
Hubei Univ, Key Lab Synth & Applicat Organ Funct Mol, Minist Educ, Wuhan 430062, Peoples R China
Hubei Univ, Coll Chem & Chem Engn, Wuhan 430062, Peoples R China Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Wuhan 430062, Peoples R China

Ding, Yu
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h-index: 0
机构:
Hubei Engn Univ, Coll Chem & Mat Sci, Xiaogan 432000, Peoples R China Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Wuhan 430062, Peoples R China
机构:
[1] Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Wuhan 430062, Peoples R China
[2] Hubei Univ, Key Lab Synth & Applicat Organ Funct Mol, Minist Educ, Wuhan 430062, Peoples R China
[3] Hubei Univ, Coll Chem & Chem Engn, Wuhan 430062, Peoples R China
[4] Hubei Engn Univ, Coll Chem & Mat Sci, Xiaogan 432000, Peoples R China
基金:
中国国家自然科学基金;
关键词:
Cu2O@Pt core-shell nanoparticles;
Non-enzymatic sensor;
Dopamine;
Ascorbic acid;
Uric acid;
OXYGEN REDUCTION REACTION;
GLASSY-CARBON ELECTRODE;
FILM-MODIFIED ELECTRODE;
REDUCED GRAPHENE OXIDE;
AU-NANOCLUSTERS;
COMPOSITE FILM;
FUEL-CELLS;
SENSOR;
CU;
NANOTUBES;
D O I:
10.1016/j.jallcom.2016.07.322
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
The Cu2O@Pt nanoparticles were prepared by a two-step method, using Vulcan XC-72 carbon as support (donated as Cu2O@Pt/C). Transmission electron microscopy, X-ray diffraction and X-ray photoelectron spectroscopy were used to characterize the resulting Cu2O@Pt core-shell nanoparticles. The chemically modified electrode based on Cu2O@Pt/C nanocomposites was employed to eliminate the interference from ascorbic acid and uric acid for the sensitive and selective determination of dopamine. The electrochemical results indicate that the Cu2O@Pt/C nanocomposites show better electrocatalytic activity for the oxidation of dopamine than Pt/C nanocomposites with a linear range from 10 nM to 1027.16 mu M, a detection limit of 3 nM (S/N = 3) and sensitivity of 638.0 mu A mM(-1) cm(-2). Moreover, the sensor exhibits excellent long-time stability, good reproducibility and can be applied for practical application. (C) 2016 Elsevier B. V. All rights reserved.
引用
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页码:174 / 181
页数:8
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