Synthesis of (E)-1-aryl-1-alkenes via a novel BF3•OEt2-catalyzed Aldol-Grob reaction sequence

被引:31
作者
Kabalka, GW [1 ]
Li, NS
Tejedor, D
Malladi, RR
Trotman, S
机构
[1] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA
[2] Univ Tennessee, Dept Radiol, Knoxville, TN 37996 USA
关键词
D O I
10.1021/jo9822784
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The reactions of aromatic aldehydes with ketones in the presence of various acids were examined. The reactions generate (E)-1-aryl-1-alkenes in the presence of boron trifluoride diethyl etherate in nonnucleophilic solvents.
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页码:3157 / 3161
页数:5
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