A new type copper(II)-gadolinium(III) complex of phenol-based side-off type dinucleating ligand containing fully saturated amino nitrogens as coordinating atoms

被引：6

作者：

Manseki, K ^{[1
]}

Sakiyama, H

Sakamoto, M

Nishida, Y

Aono, H

Sadaoka, Y

Ohba, M

Okawa, H

机构：

[1] Yamagata Univ, Grad Sch Sci & Engn, Yamagata 9908560, Japan

[2] Yamagata Univ, Fac Sci, Dept Mat & Biol Chem, Yamagata 9908560, Japan

[3] Ehime Univ, Fac Engn, Dept Mat Sci & Engn, Matsuyama, Ehime 7908577, Japan

[4] Kyushu Univ, Fac Sci, Dept Chem, Higashi Ku, Fukuoka 8128581, Japan

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 2001年 / 31卷 / 08期

基金：

日本学术振兴会;

关键词：

D O I：

10.1081/SIM-100107209

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The copper(II)-gadolinium(III) complex of a phenol-based side-off type di-nucleating ligand was newly synthesized, using N, N'-dimethyl-N,N'-ethylene-di(5-bromo-3-formyl-2-hydroxybenzylamine). Structural analysis revealed that one of the two formyl groups is converted into a hemiacetal group and the two dinuclear CuGd units are bridged by the alcoholic oxygens of acetal groups of each unit to construct the tetranuclear (CuGd)(2) core.

引用

页码：1443 / 1451

页数：9