Hydrothermal Syntheses and Crystal Structures of Three Lanthanide(III) Complexes Based on Carboxyl Derivatives of 1,10-Phenanthroline

被引：7

作者：

Qiao Yu ^{[1
]}

Wei Bing ^{[1
]}

Li Xiu-Ying ^{[1
]}

Che Guang-Bo ^{[1
]}

Liu Chun-Bo ^{[2
]}

Zhang Xing-Jing ^{[1
]}

Zhu En-Wei ^{[1
]}

Liu Feng ^{[1
]}

机构：

[1] Jilin Normal Univ, Minist Educ, Key Lab Preparat & Applicat Environm Friendly Mat, Changchun 130103, Peoples R China

[2] Jiangsu Univ, Inst Green Chem & Chem Technol, Zhenjiang 212013, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2017年 / 36卷 / 01期

基金：

中国国家自然科学基金;

关键词：

lanthanide(III) complex; 2-(4-carboxyphenyl)imidazo(4,5-f)(1,10)phenanthroline; benzene-1,4-dicarboxylic acid; crystal structure; luminescence; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; ACID; LIGAND; DECARBOXYLATION; SERIES;

D O I：

10.14102/j.cnki.0254-5861.2011-1259

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three lanthanide(III) complexes [Ln(4-NCP)(1,4-BDC)]n center dot xnH(2)O (Ln = Pr (1), Sm(2), Nd (3). 4-HNCP = 2-(4-carboxyphenyl)imidazo(4,5-f)(1,10) phenanthroline, 1,4-H2BDC = benzene-1,4-dicarboxylic acid) have been hydrothermally synthesized and characterized via elemental analysis, infrared spectrometry and single-crystal X-ray diffraction. Structural analyses revealed that complexes 1 similar to 3 possess similar porous three-dimensional frameworks with the point symbol {4(12).(63)}. Meanwhile, complexes 1 similar to 3 exhibit excellent thermal stabilities and complex 2 exhibits characteristic luminescent property.

引用

页码：73 / 81

页数：9

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