Radical Cyanation of Alkyl Iodides with Diethylphosphoryl Cyanide

被引：9
作者：
Cho, Chang Ho [1 ]
Lee, Jin Young [1 ]
Kim, Sunggak [1 ]
机构：
[1] Korea Adv Inst Sci & Technol, Dept Chem, Sch Mol Sci BK 21, Taejon 305701, South Korea
来源：
SYNLETT | 2009年 / 01期
关键词：
radical; cyanide; elimination; alkyl halides; BETA-ELIMINATION; CARBONYL GROUP; ACYLPHOSPHONATE DERIVATIVES; CYCLIZATION REACTIONS; HYPOPHOSPHOROUS ACID; PHOSPHONATE GROUP; NITROGEN BONDS; TIN; AZIDATION; PSEUDOHALOGENATION;
D O I：
10.1055/s-0028-1087385
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The beta-elimination of an organophosphoryl group from an iminyl radical is observed for the first time. On the basis of this finding, radical cyanation of alkyl iodides is achieved by using diethylphosphoryl cyanide.
引用
收藏
页码：81 / 84
页数：4
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