High open circuit voltage organic photovoltaic cells fabricated using 9,9′-bifluorenylidene as a non-fullerene type electron acceptor

被引：55

作者：

Kim, Hee Un ^{[1
,2
]}

Kim, Ji-Hoon ^{[1
,2
]}

Suh, Hongsuk ^{[1
,2
]}

Kwak, Jeonghun ^{[3
]}

Kim, Dongwook ^{[4
]}

Grimsdale, Andrew C. ^{[5
]}

Yoon, Sung Cheol ^{[6
]}

Hwang, Do-Hoon ^{[1
,2
]}

机构：

[1] Pusan Natl Univ, Dept Chem, Pusan 609735, South Korea

[2] Pusan Natl Univ, Chem Inst Funct Mat, Pusan 609735, South Korea

[3] Dong A Univ, Dept Elect Engn, Pusan 604714, South Korea

[4] Kyonggi Univ, Dept Chem, Suwonsi 443760, Gyeonggi, South Korea

[5] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore

[6] Korea Res Inst Chem Technol, Adv Mat Div, Taejon 305600, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 93期

基金：

新加坡国家研究基金会;

关键词：

SOLAR-CELLS; DERIVATIVES; POLYMERS;

D O I：

10.1039/c3cc46557h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have found that 9,9'BF can be used as an electron acceptor for P3HT-based OPVs while similar devices using 4,4'BP do not show any photovoltaic effect. This can be related to the respective aromaticity and antiaromaticity of the reduced forms of 9,9'BF or 4,4'BP. The OPV device fabricated using P3HT and 9,9'BF exhibited a PCE of 2.28% with a V-oc of 1.07 V, a J(sc) of 5.04 mA cm(-2), and a FF of 0.42.

引用

页码：10950 / 10952

页数：3

共 25 条

[1] THE SYMMETRICAL DIANTHRYLS .3.
BELL, F
WARING, DH
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1949, (OCT): : 2689 - 2693
[2] Biedermann PU, 2001, EUR J ORG CHEM, V2001, P15
[3] Solution-Processed Organic Solar Cells with Power Conversion Efficiencies of 2.5% using Benzothiadiazole/Imide-Based Acceptors
Bloking, Jason T.
Han, Xu
Higgs, Andrew T.
Kastrop, John P.
Pandey, Laxman
Norton, Joseph E.
Risko, Chad
Chen, Cynthia E.
Bredas, Jean-Luc
McGehee, Michael D.
Sellinger, Alan
[J]. CHEMISTRY OF MATERIALS, 2011, 23 (24) : 5484 - 5490
[4] Strain and Huckel Aromaticity: Driving Forces for a Promising New Generation of Electron Acceptors in Organic Electronics
Brunetti, F. G.
Gong, X.
Tong, M.
Heeger, A. J.
Wudl, Fred
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (03) : 532 - 536
[5] "Deconvoluted Fullerene" Derivatives: Synthesis and Characterization
Brunetti, Fulvio G.
Varotto, Alessandro
Batara, Nicolas A.
Wudl, Fred
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (31) : 8604 - 8608
[6] STABLE POLYCYCLIC ANIONS - DIANIONS FROM OVERCROWDED ETHYLENES
COHEN, Y
KLEIN, J
RABINOVITZ, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (14) : 1071 - 1073
[7] Beyond superquenching: Hyper-efficient energy transfer from conjugated polymers to gold nanoparticles
Fan, CH
Wang, S
Hong, JW
Bazan, GC
Plaxco, KW
Heeger, AJ
[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2003, 100 (11) : 6297 - 6301
[8] Bulk Heterojunction Solar Cells with Large Open-Circuit Voltage: Electron Transfer with Small Donor-Acceptor Energy Offset
Gong, Xiong
Tong, Minghong
Brunetti, Fulvio G.
Seo, Junghwa
Sun, Yanming
Moses, Daniel
Wudl, Fred
Heeger, Alan J.
[J]. ADVANCED MATERIALS, 2011, 23 (20) : 2272 - +
[9] X-RAY CRYSTALLOGRAPHIC MEASUREMENTS ON SOME COMPOUNDS SHOWING INTRAMOLECULAR OVERCROWDING
HARNIK, E
HERBSTEIN, FH
SCHMIDT, GMJ
[J]. NATURE, 1951, 168 (4265) : 158 - 160
[10] Diketopyrrolopyrroles as Acceptor Materials in Organic Photovoltaics
Karsten, Bram P.
Bijleveld, Johan C.
Janssen, Rene A. J.
[J]. MACROMOLECULAR RAPID COMMUNICATIONS, 2010, 31 (17) : 1554 - 1559

← 1 2 3 →