The Construction of Two New Co(II) Coordination Polymers Via Dicarboxylate and N-Donor Coligands

被引：4

作者：

Zhang, Miaomiao ^{[1
]}

Guo, Feng ^{[1
]}

机构：

[1] Dezhou Univ, Key Lab Coordinat Chem & Funct Mat Univ Shandong, Dezhou 253023, Shandong, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2013年 / 43卷 / 08期

关键词：

cobalt(II); coordination polymer; crystal structure; CRYSTAL-STRUCTURES; LIGANDS;

D O I：

10.1080/15533174.2012.753625

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel metal coordination polymers [Co(L-1)(bib)](n) (1) and [Co(L-2)(bib)]n (2) [H2L1 = 5-hydroxyisophthalic acid, H2L2 = 5-nitroisophthalic acid, and bib = 1,4-bis (2-methyl-imidazol-1-yl)butane] have been successfully synthesized and structurally characterized by IR, elemental analysis, and X-ray diffraction. Compound 1 shows a 2D layer structure and compound 2 is a 3-fold interpenetrated 3D dmp topology. The results suggest that the 5-position group affects the structure of coordination polymers.

引用

页码：1040 / 1044

页数：5

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