Synthesis and Morphology Control of Nanoporous Cu2O/Cu and Their Application as Electrode Materials for Capacitors

被引：9

作者：

Li, Yuanwei ^{[1
]}

Zhao, Xueyang ^{[1
]}

Liu, Hui ^{[1
]}

Li, Wei ^{[1
,2
]}

Wang, Xiaojian ^{[1
]}

机构：

[1] Jinan Univ, Inst Adv Wear & Corros Resistant & Funct Mat, Guangzhou 510632, Guangdong, Peoples R China

[2] Natl Joint Engn Ctr High Performance Wear Resista, Guangzhou 510632, Guangdong, Peoples R China

来源：

NANOMATERIALS | 2019年 / 9卷 / 03期

基金：

国家重点研发计划;

关键词：

nanoporous metals; dealloying; ligament size; copper; FABRICATION; COPPER; PERFORMANCE; AU; AG; CU; NANOCOMPOSITE; EVOLUTION; ALLOYS; ARRAYS;

D O I：

10.3390/nano9030340

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this paper, nanoporous copper (NPC) was prepared by dealloying ZrCuAl metallic glass ribbons with HF acid solutions. The effect of dealloying time on the porous structures and thickness of the obtained NPC films was investigated. It was found that the ligament sizes of the NPC could be tuned in a range from 20 to 300 nm, and the thicknesses of the NPC films from 3.1 to 14.4 mu m, with properly selected dealloying times. Furthermore, nanoporous composites made of NPC and nanoporous Cu2O were prepared by oxidizing the NPC with ethanol. The nanoporous composite electrodes exhibited superior charge-discharge performance and would have broad potential applications in flexible high-performance energy storage devices.

引用

页数：12

共 36 条

[31] Preparation of binder-free CuO/Cu2O/Cu composites: a novel electrode material for supercapacitor applications [J].

Xu, Panpan ;

Liu, Jijun ;

Liu, Tong ;

Ye, Ke ;

Cheng, Kui ;

Yin, Jinling ;

Cao, Dianxue ;

Wang, Guiling ;

Li, Qiang .

RSC ADVANCES, 2016, 6 (34) :28270-28278

[32] Nanoporous metals: fabrication strategies and advanced electrochemical applications in catalysis, sensing and energy systems [J].

Zhang, Jintao ;

Li, Chang Ming .

CHEMICAL SOCIETY REVIEWS, 2012, 41 (21) :7016-7031

[33] Generalized Fabrication of Nanoporous Metals (Au, Pd, Pt, Ag, and Cu) through Chemical Dealloying [J].

Zhang, Zhonghua ;

Wang, Yan ;

Qi, Zhen ;

Zhang, Wenhua ;

Qin, Jingyu ;

Frenzel, Jan .

JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (29) :12629-12636

[34] Nanoporous Gold Ribbons with Bimodal Channel Size Distributions by Chemical Dealloying of Al-Au Alloys [J].

Zhang, Zhonghua ;

Wang, Yan ;

Qi, Zhen ;

Lin, Jikui ;

Bian, Xiufang .

JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (04) :1308-1314

[35] On the electrochemical dealloying of Mg-Cu alloys in a NaCl aqueous solution [J].

Zhao, Changchun ;

Wang, Xiaoguang ;

Qi, Zhen ;

Ji, Hong ;

Zhang, Zhonghua .

CORROSION SCIENCE, 2010, 52 (12) :3962-3972

[36] Highly conductive three-dimensional MnO2-carbon nanotube-graphene-Ni hybrid foam as a binder-free supercapacitor electrode [J].

Zhu, Guoyin ;

He, Zhi ;

Chen, Jun ;

Zhao, Jin ;

Feng, Xiaomiao ;

Ma, Yanwen ;

Fan, Quli ;

Wang, Lianhui ;

Huang, Wei .

NANOSCALE, 2014, 6 (02) :1079-1085

← 1 2 3 4 →