Synthesis of a novel phosphorus-nitrogen-containing intumescent flame retardant and its application to fabrics

被引:24
作者
Jiang, Wei [1 ]
Jin, Fan-Long [1 ,2 ]
Park, Soo-Jin [2 ]
机构
[1] Jilin Inst Chem Technol, Dept Polymer Mat, Jilin 132022, Peoples R China
[2] Inha Univ, Dept Chem, Inchon 402751, South Korea
关键词
Phosphorus; Nitrogen; Intumescent flame retardant; Fabrics; Flame-retardant properties; EPOXY-RESINS; MECHANICAL-PROPERTIES; THERMAL-PROPERTIES; STABILITIES; PERFORMANCE; COMPOSITES; OIL;
D O I
10.1016/j.jiec.2015.01.010
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel phosphorus-nitrogen-containing intumescent flame retardant (IFR), ditrimethylolpropane di-N-hydroxyethyl phosphoramide (DDP), was successfully synthesized and used as a flame retardant for various fabrics. The chemical structure of DDP was characterized using FT-IR, H-1 NMR, P-31 NMR, and elemental analysis. The thermal property of DDP was investigated by thermogravimetric analysis. The effect of DDP on the flame-retardant properties of fabrics was evaluated by measurement of the burning length. The optimal synthesis conditions for DDP were determined. DDP showed high flame retardancy when applied to nylon and moderate flame retardancy when applied to cotton and polyester. (C) 2015 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:40 / 43
页数:4
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