An efficient cleavage of the aryl ether C-O bond in supercritical carbon dioxide-water

被引：52

作者：

Chatterjee, Maya ^{[1
]}

Ishizaka, Takayuki ^{[1
]}

Suzuki, Akira ^{[1
]}

Kawanami, Hajime ^{[1
]}

机构：

[1] AIST, Res Ctr Compact Chem Syst, Miyagino Ku, Toho Ku, Sendai, Miyagi, Japan

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 40期

关键词：

CATALYTIC HYDROGENOLYSIS; LIGNIN; NICKEL; HYDROGENATION; HYDRODEOXYGENATION; SELECTIVITY;

D O I：

10.1039/c3cc41522h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple and highly efficient Rh/C catalyzed route for the cleavage of the C-O bond of aromatic ether at 80 degrees C in the presence of 0.5 MPa of H-2 in the scCO(2)-water medium is reported; CO2 pressure and water play a key role under the tested conditions.

引用

页码：4567 / 4569

页数：3

共 19 条

[1]

Bercedo P. a., 2010, J AM CHEM SOC, V132, P17352

[2] An attempt to achieve the direct hydrogenolysis of tetrahydrofurfuryl alcohol in supercritical carbon dioxide [J].

Chatterjee, Maya ;

Kawanami, Hajime ;

Ishizaka, Takayuki ;

Sato, Masahiro ;

Suzuki, Toshishige ;

Suzuki, Akira .

CATALYSIS SCIENCE & TECHNOLOGY, 2011, 1 (08) :1466-1471

[3] Electrocatalytic hydrogenation of 4-phenoxyphenol on active powders highly dispersed in a reticulated vitreous carbon electrode [J].

Dabo, P ;

Cyr, A ;

Lessard, J ;

Brossard, L ;

Ménard, H .

CANADIAN JOURNAL OF CHEMISTRY, 1999, 77 (07) :1225-1229

[4] Catalytic hydrodeoxygenation [J].

Furimsky, E .

APPLIED CATALYSIS A-GENERAL, 2000, 199 (02) :147-190

[5] Ni-Catalyzed Cleavage of Aryl Ethers in the Aqueous Phase [J].

He, Jiayue ;

Zhao, Chen ;

Lercher, Johannes A. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (51) :20768-20775

[6] Nickel-Mediated Hydrogenolysis of C-O Bonds of Aryl Ethers: What Is the Source of the Hydrogen? [J].

Kelley, Paul ;

Lin, Sibo ;

Edouard, Guy ;

Day, Michael W. ;

Agapie, Theodor .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (12) :5480-5483

[7] ETHER CLEAVAGE WITH ORGANO-ALKALI-METAL COMPOUNDS AND ALKALI-METALS [J].

MAERCKER, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1987, 26 (10) :972-989

[8] Formation of Ni[C4(CN)8] from the reaction of Ni(COD)2 (COD=1,5cyclooctadiene) with TCNE in THF [J].

Miller, Joel S. ;

Pokhodnya, Konstantin I. .

JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (34) :3585-3587

[9] Catalytic hydrogenolysis of ethanol organosolv lignin [J].

Nagy, Mate ;

David, Kasi ;

Britovsek, George J. P. ;

Ragauskas, Arthur J. .

HOLZFORSCHUNG, 2009, 63 (05) :513-520

[10]

Rylander P. N., 1968, ENGELHARD IND TECH B, V9, P14

← 1 2 →