Design of Micro/Mesoporous Zeolite-Based Catalysts for Petrochemical and Organic Syntheses

被引:14
作者
Ivanova, I. I. [1 ,2 ]
Knyazeva, E. E. [1 ,2 ]
Maerle, A. A. [1 ]
Kasyanov, I. A. [1 ]
机构
[1] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119991, Russia
[2] Russian Acad Sci, AV Topchiev Petrochem Synth Inst, Moscow 119991, Russia
基金
俄罗斯科学基金会;
关键词
zeolites; micro/mesoporous materials; recrystallization; acidic properties; catalytic activity; MESOPOROUS MOLECULAR-SIEVES; HIGH HYDROTHERMAL STABILITY; HIERARCHICAL POROSITY; ZSM-5/MCM-41; COMPOSITE; BETA/MCM-41; DIMETHYL ETHER; ZSM-5; ZEOLITE; SILICIC GELS; FCC CATALYST; Y ZEOLITE;
D O I
10.1134/S0023158415030088
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This review systematizes and analyzes the physicochemical and catalytic properties of micro/mesoporous materials prepared by two-step recrystallization. The materials are divided into three groups according to the degree of recrystallization: (1) mesostructured zeolites (RZEO-1), (2) micro/mesoporous nanocomposites (RZEO-2), and (3) mesoporous materials with zeolite fragments (RZEO-3). Particular attention is focused on the catalytic properties of the recrystallized materials in petrochemical and organic syntheses. Main advantages of the micro/mesoporous molecular sieves over zeolites and mesoporous materials are demonstrated, and ways of obtaining new catalytic systems based on these molecular sieves are suggested.
引用
收藏
页码:549 / 561
页数:13
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