Asymmetric [N-I-N]+halonium complexes

被引：45

作者：

Ward, Jas S. ^{[1
]}

Fiorini, Giorgia ^{[1
]}

Frontera, Antonio ^{[2
]}

Rissanen, Kari ^{[1
]}

机构：

[1] Univ Jyvaskyla, Dept Chem, Jyvaskyla 40014, Finland

[2] Univ Illes Balears, Dept Chem, Crts Valldemossa Km 7-6, Palma De Mallorca 07122, Baleares, Spain

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 60期

关键词：

LEWIS-BASE ADDUCTS; METAL(I) COMPOUNDS; HALOGEN BONDS; CAPSULES; REAGENTS;

D O I：

10.1039/d0cc02758h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first asymmetric halogen-bonded iodonium complexes [I(py)(4-DMAP)]PF6(2c) and [I(py)(4-Etpy)]PF6(2e) were preparedvia[N-Ag-N](+)-> [N-I-N](+)cation exchange of their analogous 2-coordinate silver complexes. The complexes were characterised by(1)H and(1)H-N-15 HMBC NMR spectroscopy, and single crystal X-ray crystallography.

引用

页码：8428 / 8431

页数：4

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