Edge-Sharing BO4 Tetrahedra in the Structure of Hydrothermally Synthesized Barium Borate: α-Ba3[B10O17(OH)2]

被引：21
|
作者：
Jen, I-Hsuan [1 ]
Lee, Yi-Chang [1 ]
Tsai, Cheng-En [1 ]
Lii, Kwang-Hwa [1 ,2 ]
机构：
[1] Natl Cent Univ, Dept Chem, Zhongli 320, Taiwan
[2] Acad Sinica, Inst Chem, Taipei 115, Taiwan
来源：
INORGANIC CHEMISTRY | 2019年 / 58卷 / 07期
关键词：
CRYSTAL-STRUCTURE; REFINEMENT; OXOBORATE; POLYANION;
D O I：
10.1021/acs.inorgchem.9b00345
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two polymorphs of a new barium borate, alpha- and beta-Ba-3[B10O17(OH)(2)], have been synthesized through hydrothermal reactions at 500 degrees C and 1000 bar and their structures determined by single-crystal X-ray diffraction. The 3D framework structure of the alpha-form is formed of two different fundamental building blocks (FBB) with the descriptors 4 Delta 6 square[(sic)(sic)]- <3 square>- <2 Delta square>1-<3 square>-<2 Delta square>1 and 2030:<020> <020>. The former FBB is unique and contains unusual edge-sharing B04 tetrahedra. The /3 form has a double layer structure which is formed of two stereoisomers of a pentaborate polyanion with the descriptor 2030:<6.20> <[120>. Within a double layer, one sheet composed of FBBs in 1 configuration is connected by sharing tetrahedral vertices to the other sheet of FBBs in d configuration. The a-form is the first compound with edge-sharing B04 tetrahedra synthesized in aqueous solution under hydrothermal conditions.
引用
收藏
页码：4085 / 4088
页数：4
相关论文
共 50 条
  • [31] Synthesis and characterization of the first hydrothermally synthesized tin borate Sn2B3O6(OH)
    Schoenegger, Sandra
    Wurst, Klaus
    Heymann, Gunter
    Schaur, Andreas
    Saxer, Andreas
    Johrendt, Dirk
    Huppertz, Hubert
    JOURNAL OF SOLID STATE CHEMISTRY, 2018, 258 : 410 - 415
  • [32] [O2Pb3]2(BO3)Br: An Oxidoborate Oxide Bromide with the ∞1[O2Pb3] Double Chains Based on Edge-sharing OPb4 Tetrahedra
    Dong, Lingyun
    Yang, Jiao
    Shen, Shigang
    Liu, Zhenzhen
    Chen, Xiaojing
    Sun, Sufang
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2017, 643 (07): : 471 - 476
  • [33] Chains of edge-sharing OPb4 tetrahedra in the structure of Pb4O(VO4)2 and in related minerals and inorganic compounds
    Krivovichev, SV
    Burns, PC
    CANADIAN MINERALOGIST, 2003, 41 : 951 - 958
  • [34] Rb5Ba2(B10O17)2(BO2): The formation of unusual functional [BO2]− in borates with deep-ultraviolet transmission window
    Yanhui Zhang
    Fuming Li
    Rong Yang
    Yun Yang
    Fangfang Zhang
    Zhihua Yang
    Shilie Pan
    Science China Chemistry, 2022, 65 : 719 - 725
  • [35] Rb5Ba2(B10O17)2（BO2）:Theformationofunusualfunctional[BO2]-inborateswithdeep-ultraviolettransmissionwindow<iclass="icon-zqcb"></i>
    Yanhui Zhang
    Fuming Li
    Rong Yang
    Yun Yang
    Fangfang Zhang
    Zhihua Yang
    Shilie Pan
    Science China(Chemistry), 2022, 65 (04) : 719 - 725
  • [36] Rb5Ba2(B10O17)2(BO2): The formation of unusual functional [BO2]~- in borates with deep-ultraviolet transmission window
    Yanhui Zhang
    Fuming Li
    Rong Yang
    Yun Yang
    Fangfang Zhang
    Zhihua Yang
    Shilie Pan
    Science China(Chemistry), 2022, (04) : 719 - 725
  • [37] Rb5Ba2(B10O17)2(BO2): The formation of unusual functional [BO2]- in borates with deep-ultraviolet transmission window
    Zhang, Yanhui
    Li, Fuming
    Yang, Rong
    Yang, Yun
    Zhang, Fangfang
    Yang, Zhihua
    Pan, Shilie
    SCIENCE CHINA-CHEMISTRY, 2022, 65 (04) : 719 - 725
  • [38] Ca10Na10[Te9O42](H2O): a hydrothermally synthesized quaternary tellurium(VI) oxide containing edge-sharing octahedral trimers
    Zhang, Li-Yun
    Lii, Kwang-Hwa
    DALTON TRANSACTIONS, 2019, 48 (40) : 15239 - 15243
  • [39] Crystal structure of barium bis(nitrilotriacetato)cobaltate(III), Ba3[Co(Nta)2]2 • 10H2O
    Zabel, M.
    Poznyak, A. L.
    Pawlowski, V. I.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2008, 34 (08) : 594 - 598
  • [40] Crystal structure of barium bis(nitrilotriacetato)cobaltate(III), Ba3[Co(Nta)2]2 · 10H2O
    M. Zabel
    A. L. Poznyak
    V. I. Pawlowski
    Russian Journal of Coordination Chemistry, 2008, 34 : 594 - 598
12345