Packing of Isophthalate Tetracarboxylic Acids on Au(111): Rows and Disordered Herringbone Structures

被引：11

作者：

Cebula, Izabela ^{[1
,2
,3
]}

Smith, Emily F. ^{[2
]}

Gimenez-Lopez, Maria del Carmen ^{[2
]}

Yang, Sihai ^{[2
]}

Schroeder, Martin ^{[2
]}

Champness, Neil R. ^{[2
]}

Beton, Peter H. ^{[1
]}

机构：

[1] Univ Nottingham, Sch Phys & Astron, Nottingham NG7 2RD, England

[2] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

[3] Univ Wroclaw, Inst Expt Phys, PL-50204 Wroclaw, Poland

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2013年 / 117卷 / 36期

基金：

英国工程与自然科学研究理事会;

关键词：

TRIMESIC ACID; HYDROGEN; GROWTH; ADSORPTION;

D O I：

10.1021/jp402333m

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Scanning tunnelling microscopy (STM) has been used to investigate the formation of hydrogen-bonded structures of the isophthalate tetracarboxylic acids, biphenyl-3,3 '',5,5 ''-tetracarboxylic acid (BPTC), terphenyl-3,3 '',5,5 ''-tetracarboxylic acid (TPTC), and quarterphenyl-3,3''',5,5'''-tetracarboxylic acid (QPTC), via deposition from solution onto Au(111). STM data reveal that ordered structures can be formed from an aqueous solution leading to the formation of rows for the shortest acid BPTC, while the longer molecules TPTC and QPTC adopt a herringbone-like structure with significant degrees of disorder. The influence of solvent and substrate on the molecular ordering is discussed, and density functional theory is used to identify molecular models for these new phases.

引用

页码：18381 / 18385

页数：5

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