Highly efficient oxidation of sulfides with sodium periodate catalyzed by reusable silica supported Mn(Br8TPP)Cl and Mn(TPP)Cl catalysts under various reaction conditions

被引：44

作者：

Mirkhani, Valiollah ^{[1
]}

Moghadam, Majid ^{[1
]}

Tangestaninejad, Shahram ^{[1
]}

Mohammdpoor-Baltork, Iraj ^{[1
]}

Kargar, Hadi ^{[2
]}

Araghi, Mehdi ^{[1
]}

机构：

[1] Univ Isfahan, Catalysis Div, Dept Chem, Esfahan 8174673441, Iran

[2] Payame Noor Univ, Ardakan, Yazd, Iran

来源：

APPLIED CATALYSIS A-GENERAL | 2009年 / 353卷 / 01期

关键词：

Sulfide; Periodate; Sulfoxide; Sulfone; Metalloporphyrin; ALKENE EPOXIDATION; MANGANESE PORPHYRIN; ALKANE HYDROXYLATION; HYDROCARBON OXIDATION; HOMOGENEOUS SOLUTION; OLEFIN EPOXIDATION; HANTZSCH 1,4-DIHYDROPYRIDINES; HETEROGENEOUS CATALYST; BIOMIMETIC OXIDATION; HYDROGEN-PEROXIDE;

D O I：

10.1016/j.apcata.2008.10.021

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Silica supported octabromotetraphenylporphyrinatomanganese (III) chloride, Mn(Br8TPP)Cl-Silm, and tetraphenylporphyrinatomangenese (III) chloride, Mn(TPP)Cl-Silm were used as heterogeneous catalysts for biomimetic oxidation of sulfides with NaIO4 under agitation with magnetic stirring and sulfoxides and sulfones were obtained as products in high to excellent yields. Ultrasonic irradiation enhanced the catalytic activity of these catalysts in the oxidation of sulfides, reduced the reaction times and increased the product yields. Linear sulfides were completely converted to sulfones while aromatic and cyclic sulfides produced the sulfoxide and sulfone. These new heterogenized Catalysts Could be reused several times without significant loss of their catalytic activity. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：61 / 67

页数：7

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