Effects of solid additives on the control of trace elements during coal gasification

被引：0

作者：

Huang, YJ ^{[1
]}

Jin, BS ^{[1
]}

Zhong, ZP ^{[1
]}

Xiao, R ^{[1
]}

Zhou, HC ^{[1
]}

机构：

[1] Southeast Univ, Educ Minist Key Lab Clean Coal Power Generat & Co, Nanjing 210096, Peoples R China

来源：

CIRCULATING FLUIDIZED BED TECHNOLOGY VIII | 2005年

关键词：

trace elements; solid additives; control; coal gasification; geo-chemical enrichment factor;

D O I：

暂无

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Based on the Modified Geo-chemical Enrichment Factor (MGEF), the contents of As, Cd, Co, Cr, Cu, Mn, Hg, Pb, V, Se, Sr, Zn in coal and coal char were analyzed by using HG-AFS and ICP-AES. Limestone, dolomite and sodium carbonate were studied to control trace elements during coal gasification. Different additives show different performances in the control of trace elements. The adsorbing capacity of coal char to all of trace elements enhances when coal is mixed with limestone and dolomite. Chemical adsorption and physical adsorption of lime, which is decomposition product of limestone under high gasification temperature, are both important for As, Co, Cr, Se and Zn. The effects of limestone on Cd, Cu, Hg, Pb, V and Sr are merely caused by physical adsorption of CaO and the adsorbing capacity to Cd, Cu, V is much stronger than those to Hg, Pb, Sr. Dolomite has stronger adsorbing capacity to most of elements (except Cu, Se, Sr) than limestone. Addition of Na2CO3 decreases the MGEFs of As, Cd, Cr, Pb and Se while increases the MGEFs of Zn in coal char. Na2CO3 has little effect on the MGEFs of Co, Cu, Hg, V and Sr in coal char.

引用

页码：544 / 551

页数：8

共 16 条

[1] Importance of geomorphology and sedimentation processes for metal dispersion in sediments and soils of the Ganga Plain: identification of geochemical domains [J].