An Aqueous Rechargeable Lithium Battery Using Coated Li Metal as Anode

被引：154

作者：

Wang, Xujiong ^{[1
]}

Hou, Yuyang ^{[1
]}

Zhu, Yusong ^{[1
]}

Wu, Yuping ^{[1
]}

Holze, Rudolf ^{[2
]}

机构：

[1] Fudan Univ, Dept Chem, NEML, Shanghai 200433, Peoples R China

[2] Tech Univ Chemnitz, Inst Chem, AG Elektrochem, D-09107 Chemnitz, Germany

来源：

SCIENTIFIC REPORTS | 2013年 / 3卷

关键词：

MEMBRANE; SULFUR;

D O I：

10.1038/srep01401

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

New energy industry including electric vehicles and large-scale energy storage in smart grids requires energy storage systems of good safety, high reliability, high energy density and low cost. Here a coated Li metal is used as anode for an aqueous rechargeable lithium battery (ARLB) combining LiMn2O4 as cathode and 0.5 mol l(-1) Li2SO4 aqueous solution as electrolyte. Due to the "cross-over'' effect of Li+ ions in the coating, this ARLB delivers an output voltage of about 4.0 V, a big breakthrough of the theoretic stable window of water, 1.229 V. Its cycling is very excellent with Coulomb efficiency of 100% except in the first cycle. Its energy density can be 446 Whkg(-1), about 80% higher than that for traditional lithium ion battery. Its power efficiency can be above 95%. Furthermore, its cost is low and safety is much reliable. It provides another chemistry for post lithium ion batteries.

引用

页数：5

共 29 条

[1] A New Class of Lithium and Sodium Rechargeable Batteries Based on Selenium and Selenium-Sulfur as a Positive Electrode [J].

Abouimrane, Ali ;

Dambournet, Damien ;

Chapman, Karena W. ;

Chupas, Peter J. ;

Weng, Wei ;

Amine, Khalil .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (10) :4505-4508

[2]

[Anonymous], 2012, LITHIUM ION BATTERIE

[3] Li-O2 Battery with a Dimethylformamide Electrolyte [J].

Chen, Yuhui ;

Freunberger, Stefan A. ;

Peng, Zhangquan ;

Barde, Fanny ;

Bruce, Peter G. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (18) :7952-7957

[4] REVERSAL OF POTENTIAL ACROSS A LIQUID NON-AQUEOUS MEMBRANE WITH REGARD TO MEMBRANE EXCITABILITY [J].

COLACICCO, G .

NATURE, 1965, 207 (5001) :1045-+

[5] Redox flow cells for energy conversion [J].

de Leon, C. Ponce ;

Frias-Ferrer, A. ;

Gonzalez-Garcia, J. ;

Szanto, D. A. ;

Walsh, F. C. .

JOURNAL OF POWER SOURCES, 2006, 160 (01) :716-732

[6] Electrical Energy Storage for the Grid: A Battery of Choices [J].

Dunn, Bruce ;

Kamath, Haresh ;

Tarascon, Jean-Marie .

SCIENCE, 2011, 334 (6058) :928-935

[7] Electrode materials for lithium secondary batteries prepared by sol-gel methods [J].

Fu, LJ ;

Liu, H ;

Li, C ;

Wu, YP ;

Rahm, E ;

Holze, R ;

Wu, HQ .

PROGRESS IN MATERIALS SCIENCE, 2005, 50 (07) :881-928

[8] Superionic glass-ceramic electrolytes for room-temperature rechargeable sodium batteries [J].

Hayashi, Akitoshi ;

Noi, Kousuke ;

Sakuda, Atsushi ;

Tatsumisago, Masahiro .

NATURE COMMUNICATIONS, 2012, 3

[9] Stabilizing lithium-sulphur cathodes using polysulphide reservoirs [J].

Ji, Xiulei ;

Evers, Scott ;

Black, Robert ;

Nazar, Linda F. .

NATURE COMMUNICATIONS, 2011, 2

[10] A multilayered membrane for vanadium redox flow battery [J].

Jia, Chuankun ;

Liu, Jianguo ;

Yan, Chuanwei .

JOURNAL OF POWER SOURCES, 2012, 203 :190-194

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