Synthesis of Vinylsilanes

被引：128

作者：

Lim, Diane S. W. ^{[1
]}

Anderson, Edward A. ^{[1
]}

机构：

[1] Univ Oxford, Chem Res Lab, Oxford OX1 3TA, England

来源：

SYNTHESIS-STUTTGART | 2012年 / 44卷 / 07期

基金：

英国工程与自然科学研究理事会;

关键词：

silicon; alkenes; hydrosilylation; olefination; organometallic reagents; RING-CLOSING METATHESIS; CROSS-COUPLING REACTIONS; DIVERSITY-ORIENTED SYNTHESIS; N-HETEROCYCLIC CARBENE; RUTHENIUM-CATALYZED HYDROSILYLATION; HIGHLY STEREOSELECTIVE-SYNTHESIS; STEREOCONTROLLED TOTAL-SYNTHESIS; SILICON-CONTAINING COMPOUNDS; FORMAL TOTAL-SYNTHESIS; MIXED-METAL COMPLEXES;

D O I：

10.1055/s-0031-1289729

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Vinylsilanes are versatile synthetic building blocks, which in recent years have played an increasing role in the synthesis of complex molecules. This article provides an overview of regio- and stereoselective methods for the preparation of vinylsilanes, focusing on the most flexible and synthetically practical routes to each substitution pattern.

引用

收藏

页码：983 / 1010

页数：28

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