Essential role of element Si in corrosion resistance of a bridge steel in chloride atmosphere

被引:55
作者
Liu, Haixia [1 ,2 ]
Huang, Feng [1 ,2 ]
Yuan, Wei [1 ,2 ]
Hu, Qian [1 ,2 ]
Liu, Jing [1 ,2 ]
Cheng, Y. Frank [3 ]
机构
[1] Wuhan Univ Sci & Technol, State Key Lab Refractories & Met, Wuhan 430081, Hubei, Peoples R China
[2] Wuhan Univ Sci & Technol, Hubei Engn Technol Res Ctr Marine Mat & Serv Safe, Wuhan 430081, Hubei, Peoples R China
[3] Univ Calgary, Dept Mech Engn, Calgary, AB T2N 1N4, Canada
基金
国家重点研发计划; 中国国家自然科学基金;
关键词
Corrosion resistance; Si element; Chloride atmospheric; Bridge steel; LOW-ALLOY STEELS; WEATHERING STEEL; RUST LAYER; BEHAVIOR; NI; CR; CU; PERFORMANCE; SURFACE; IRON;
D O I
10.1016/j.corsci.2020.108758
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The role of element Si in corrosion of a bridge steel was investigated in chloride atmosphere. The effect of Si addition on steel corrosion depends on the Si content and testing time. For Si-containing steels, the corrosion resistance is enhanced due to formation of SiO2 with a network structure, facilitating alpha-FeOOH formation, the reduction of the anion selectivity and enrichment of Cu and Cr in the inner rust layer. However, after long-term testing, for 0.32Si and 0.40Si steels, the unstable silicon-oxytetrahedron compound with Q(1) bond is formed, making the rust layer loose and porous, the corrosion resistance of steels reduces.
引用
收藏
页数:18
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