Synthesis and characterization of crosslinked polymers from cottonseed oil

被引:10
作者
Wijayapala, Rangana [1 ]
Mishra, Satish [1 ]
Elmore, Bill [1 ]
Freeman, Charles [2 ]
Kundu, Santanu [1 ]
机构
[1] Mississippi State Univ, Dave C Swalm Sch Chem Engn, Mississippi State, MS 39762 USA
[2] Mississippi State Univ, Sch Human Sci, Mississippi State, MS 39762 USA
关键词
biopolymers; cottonseed oil; epoxidation; polymer network; renewable polymer; SOYBEAN OIL; EPOXY-RESINS; EPOXIDATION; FATS;
D O I
10.1002/app.47655
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Traditional plastics are usually obtained from nonrenewable petroleum feedstocks. In this study, crosslinked polymers were synthesized from cottonseed oil. Unsaturated fatty acids, the major components of cottonseed oils, were initially epoxidized. A network polymer was then formed by crosslinking the epoxidized oil with maleic anhydrate. Mechanical properties of these polymers were altered by varying the amount of maleic anhydrate. These polymers have a tensile modulus of the order 1 MPa and are stable in the acidic and alkaline environment. Our results provide a new synthetic strategy to obtain a network polymer from cottonseed oil. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47655.
引用
收藏
页数:7
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