Novel and highly selective conversion of alcohols, thiols and trimethylsilyl ethers to alkyl nitrites with 2,4,6-trichloro[1,3,5]triazine/n-Bu4NNO2 system

被引：10
作者：
Akhlaghinia, B [1 ]
Roohi, E [1 ]
机构：
[1] Damghan Univ Basic Sci, Dept Chem, Damghan, Iran
来源：
LETTERS IN ORGANIC CHEMISTRY | 2006年 / 3卷 / 03期
关键词：
2,4,6-Trichloro[1,3,5] triazine(TT); alcohol; thiol; trimethylsilyl ether; alkyl nitrite;
D O I：
10.2174/157017806775789804
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Alkyl nitrites were prepared in good to excellent yields by treatment of alcohols, thiols and trimethylsilyl ethers with 2,4,6-trichloro[1,3,5]triazine/n-Bu4NNO2 in refluxing acetonitrile. This method is highly selective for the conversion of primary alcohols to alkyl nitrites in the presence of secondary and tertiary alcohols, thiols and trirnethylsilyl ethers.
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收藏
页码：220 / 224
页数：5
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