Synthesis of new functionalized poly(vinyl alcohol) hydrogel and studies of its zinc ion retention properties

被引:0
作者
Mukherjee, A. [1 ]
Singha, B. [1 ]
Chowdhury, P. [1 ]
机构
[1] Visva Bharati, Dept Chem, Santini Ketan 731235, W Bengal, India
关键词
Cross-linked graft copolymer; Zn2+; retention; ion-exchange; solid phase extraction; SOLID-PHASE EXTRACTION; REMOVING LEAD-ION; POLY(ACRYLIC ACID); MERCURY(II); ADSORPTION; WATER; ABSORPTION; COPOLYMERS; SEPARATION; EFFICIENCY;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new functionalized poly(vinly alcohol) (PVA) hydrogel (resin) has been synthesized in green aqueous medium through simple chemical method for the study of effectiveness in removing zinc ions from aqueous solution. The nature of the resin has been elucidated with the help of chemical, spectral and thermal analysis. The zinc ion uptake was studied in the light of solution pH, contact time, adsorbent dose and metal ion concentration. The resin (StyS - PVA graft copolymer) acts as a hydrogel as well as ion exchanger. The functional groups present in the resin are responsible for the retention of zinc ions. A plausible mechanism for zinc ion extraction has been suggested.
引用
收藏
页码:793 / 799
页数:7
相关论文
共 31 条
[1]   Synthesis of graft copolymeric membranes of poly(vinyl alcohol) and polyacrylamide for the pervaporation separation of water/acetic acid mixtures [J].
Aminabhavi, TA ;
Naik, HG .
JOURNAL OF APPLIED POLYMER SCIENCE, 2002, 83 (02) :244-258
[2]  
Barros J. A. G., 2011, MAT SCI APPL, V2, P1058
[3]   Adsorption of Zn(II) by crosslinked acrylic copolymers with amine functional groups [J].
Barsanescu, A ;
Buhaceanu, R ;
Dulman, V ;
Bunia, I ;
Neagu, V .
JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 93 (02) :803-808
[4]   Highly luminescent organic-inorganic hybrid mesoporous silicas containing tunable chemosensor inside the pore wall [J].
Chandra, Debraj ;
Yokoi, Toshiyuki ;
Tatsumi, Takashi ;
Bhaumik, Asim .
CHEMISTRY OF MATERIALS, 2007, 19 (22) :5347-5354
[5]   A fluorophore grafted 2D-hexagonal mesoporous organosilica: Excellent ion-exchanger for the removal of heavy metal ions from wastewater [J].
Chandra, Debraj ;
Das, Swapan Kumar ;
Bhaumik, Asim .
MICROPOROUS AND MESOPOROUS MATERIALS, 2010, 128 (1-3) :34-40
[6]  
Chowdhury P, 2005, J POLYM MATER, V22, P277
[7]   Synthesis of Graft Copolymer of Poly(acrylic acid) and Poly(vinyl alcohol) in the Presence of Methylene Bisacrylamide Crosslinker and Investigation of its Efficiency in Removing Lead Ion from Aqueous Solution [J].
Chowdhury, P. ;
Mukherjee, A. ;
Singha, B. ;
Pandit, S. K. .
JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2009, 46 (05) :547-553
[8]  
Chowdhury P., 2011, INDIAN J CHEM B, V49, P547
[9]   Studies on Hg(II) ion retention properties of cross-linked graft copolymer of acrylic acid and its analytical application [J].
Chowdhury, Pranesh ;
Mukherjee, Abhijit ;
Singha, B. ;
Mondal, Palash ;
Roy, Kousik .
JOURNAL OF POLYMER RESEARCH, 2010, 17 (06) :853-860
[10]  
Chowdhury P, 2009, J INDIAN CHEM SOC, V86, P377