A facile solvent-free synthesis route for the assembly of a highly CO2 selective and H2S tolerant NiSIFSIX metal-organic framework

被引:132
作者
Shekhah, Osama [1 ]
Belmabkhout, Youssef [1 ]
Adil, Karim [1 ]
Bhatt, Prashant M. [1 ]
Cairns, Amy J. [1 ]
Eddaoudi, Mohamed [1 ]
机构
[1] 4700 King Abdullah Univ Sci & Technol, Adv Membrane & Porous Mat Ctr, FMD3, Thuwal 239556900, Saudi Arabia
关键词
CARBON-DIOXIDE; ADSORPTION; MOF; PLATFORM; CAPTURE; GAS; AIR;
D O I
10.1039/c5cc04487a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The development of materials for CO2 capture with high selectivity and high tolerance to H2S is of prime importance for various industrially relevant gas streams (e.g. natural gas and biogas upgrading as well as pre-combustion capture). Here, we report the successful fabrication of aMOF with combined exceptional CO2 capture properties and H2S tolerance, namely the NiSIFSIX-based MOF using both solvothermal and solvent-free methodologies.
引用
收藏
页码:13595 / 13598
页数:4
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