Platinum complexes bearing a boron-based PBP pincer ligand: synthesis, structure, and application as a catalyst for hydrosilylation of 1-decene

被引：62

作者：

Ogawa, Hayato ^{[1
]}

Yamashita, Makoto ^{[1
]}

机构：

[1] Chuo Univ, Fac Sci & Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1128551, Japan

来源：

DALTON TRANSACTIONS | 2013年 / 42卷 / 03期

关键词：

BORYL COMPLEXES; OXIDATIVE ADDITION; IRON CATALYSTS; REACTIVITY; PALLADIUM; BONDS; IRIDIUM; RHODIUM; HYDROSILATION; HYDROGENATION;

D O I：

10.1039/c2dt31892j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Four platinum(II) complexes bearing a boron-based PBP pincer ligand and chloride, hydride, triflate, and bis(trifluoromethanesulfonyl)imide were synthesized and structurally characterized. PBP-platinum chloride was proven to be an active catalyst for the hydrosilylation reaction using 1-decene and triethylsilane.

引用

页码：625 / 629

页数：5

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