Platinum complexes bearing a boron-based PBP pincer ligand: synthesis, structure, and application as a catalyst for hydrosilylation of 1-decene

被引：62
|
作者：
Ogawa, Hayato [1 ]
Yamashita, Makoto [1 ]
机构：
[1] Chuo Univ, Fac Sci & Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1128551, Japan
来源：
DALTON TRANSACTIONS | 2013年 / 42卷 / 03期
关键词：
BORYL COMPLEXES; OXIDATIVE ADDITION; IRON CATALYSTS; REACTIVITY; PALLADIUM; BONDS; IRIDIUM; RHODIUM; HYDROSILATION; HYDROGENATION;
D O I：
10.1039/c2dt31892j
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Four platinum(II) complexes bearing a boron-based PBP pincer ligand and chloride, hydride, triflate, and bis(trifluoromethanesulfonyl)imide were synthesized and structurally characterized. PBP-platinum chloride was proven to be an active catalyst for the hydrosilylation reaction using 1-decene and triethylsilane.
引用
收藏
页码：625 / 629
页数：5
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