Coordination geometry around copper in a Schiff-base trinuclear copper complex using EXAFS spectroscopy

被引：1

作者：

Gaur, Abhijeet ^{[1
]}

Shrivastava, B. D. ^{[1
]}

Gaur, D. C. ^{[2
]}

Prasad, J. ^{[3
]}

Srivastava, K. ^{[3
]}

Jha, S. N. ^{[4
]}

Bhattacharyya, D. ^{[4
]}

Poswal, A. ^{[4
]}

机构：

[1] Vikram Univ, Sch Studies Phys, Ujjain 452001, Madhya Pradesh, India

[2] Govt PG Coll, Rajgrah 465611, India

[3] Univ Allahabad, Dept Chem, Allahabad 211002, Uttar Pradesh, India

[4] Bhabha Atom Res Ctr, Appl Spectroscopy Div, Bombay 400085, Maharashtra, India

来源：

INTERNATIONAL CONFERENCE ON RECENT TRENDS IN PHYSICS (ICRTP 2012) | 2012年 / 365卷

关键词：

MODEL;

D O I：

10.1088/1742-6596/365/1/012033

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

In the present investigation, we have studied extended X-ray absorption fine structure (EXAFS) spectra of a trinuclear Schiff-base copper complex tetraaqua-di-mu 3-(N-salicylidene-DL-glutamato)-tricopper(II)heptahydrate, [Cu-3(C12H10NO5)(2) (H2O)(4)]. 7H(2)O, in which three metal sites are present. One metal site is square-pyramidal (4+1) and other two similar metal sites are tetragonally distorted octahedral (4+2). EXAFS has been recorded at the K-edge of copper in the complex at the dispersive EXAFS beamline at 2 GeV Indus-2 synchrotron source at RRCAT, Indore, India. The analysis of EXAFS spectra of multinuclear metal complexes pose some problems due to the presence of many absorbing atoms, even when the absorbing atoms may be of the same element. Hence, using the available crystal structure of the complex, theoretical models have been generated for the different copper sites separately, which are then fitted to the experimental EXAFS data. The two coordination geometries around the copper sites have been determined. The contributions of the different copper sites to the experimental spectrum have been estimated. The structural parameters, which include bond-lengths, coordination numbers and thermal disorders, for the two types of copper sites have been reported. Further, copper has been found to be in +2 oxidation state at these metal sites.

引用

页数：5