Mass-production of ZnO nanoparticles by precipitation in a rotating packed bed: effect of zinc salt

The effect of three zinc salts (Zn(CH3COO)(2), ZnSO4, and Zn(NO3)(2)) on the size of the pre-cursors of the ZnO nanoparticles that were mass-produced by precipitation in a rotating packed bed was studied. The precursors were formed at a rotational speed of 2000 rpm and flow rates of 0.5 L/min by precipitation using various zinc salts and NaOH as the precipi-tant. When zinc salts were Zn(CH3COO)(2) and ZnSO4, the smallest precursors were obtained at a Zn2+/OH- molar ratio of 1/2. However, when the zinc salt was Zn(NO3)(2), the small-est precursors were obtained at a Zn2+/OH- molar ratio of 1/1. Additionally, various zinc salts yielded different effects of the concentrations of Zn2+ and OH- on the size of the pre-cursors. Experimental results indicate that the smallest precursors for various zinc salts were obtained at a Zn(CH3COO)(2) concentration of 0.4 mol/L and an NaOH concentration of 0.8 mol/L, a ZnSO4 concentration of 0.1 mol/L and an NaOH concentration of 0.2 mol/L, and a Zn(NO3)(2) concentration of 0.2 mol/L and an NaOH concentration of 0.2 mol/L. ZnO nanopar-ticles were mass-produced by calcining these precursors at sufficient temperatures for 1 h. In this way, the average sizes of the ZnO nanoparticles that were mass-produced using Zn(NO3)(2), Zn(CH3COO)(2), and ZnSO4 as zinc salts were 98, 136, and 186 nm, respectively. (C) 2020 The Author(s). Published by Elsevier B.V.