A Cationic Antimonite Chain Templated by Sulfate: [Sb6O74+] [(SO42-)2]

被引：7

作者：

Fei, Honghan ^{[1
]}

Han, Cari S. ^{[1
]}

Oliver, Scott R. J. ^{[1
]}

机构：

[1] Univ Calif Santa Cruz, Dept Chem & Biochem, Santa Cruz, CA 95064 USA

来源：

INORGANIC CHEMISTRY | 2012年 / 51卷 / 16期

基金：

美国国家科学基金会;

关键词：

RARE-EARTH HYDROXIDES; ANION-EXCHANGE; HYDROTHERMAL SYNTHESIS; LAYERED MATERIAL; FRAMEWORK; LN; FAMILY; ETHANEDISULFONATE; ZEOLITES; TB;

D O I：

10.1021/ic3013409

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An extended metal oxide possessing a cationic charge on the host has been synthesized by hydrothermal methods. The structure consists of 1D antimony oxide [Sb6O2](4+) chains with a new structural motif of four Sb atoms wide and unprotonated sulfate anions between the chains. The material was characterized by powder and single-crystal X-ray diffraction. Thermal behavior and chemical resistance in aqueous acidic conditions (pH similar to 2) indicate a highly stable cationic material. The stability is attributed to the entirely inorganic composition of the structure, where 1D covalently extended chains are electrostatically bound to divalent anions.

引用

页码：8655 / 8657

页数：3

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