Sorption characteristics of chelating resins - II. Sorption of Zn(II) and Cd(II) by Chelex 100

被引:6
|
作者
Arroza, E [1 ]
Rengan, K [1 ]
机构
[1] Eastern Michigan Univ, Dept Chem, Ypsilanti, MI 48197 USA
关键词
Sulfate; Chloride; Nitrate; H2SO4; HNO3;
D O I
10.1007/BF02345566
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Chelating resins are used for preconcentrating metal ions in trace analysis. As part of a systematic study of sorption characteristics of the chelating resin Chelex 100, the sorption of Zn(II) and Cd(II) in different aqueous media was investigated. The distribution coefficient (DC) values for both Zn(II) and Cd(II) were extremely low (<4) in 0.5 to 6M HNO3 and H2SO4 solutions. In HCl solutions, the DC values for both Zn(II) and Cd(II) were higher, reaching a peak of nearly 40 in 3M HCl solutions. The DC values for both Zn(II) and Cd(II) increased with increasing pH in chloride, nitrate, and sulfate solutions (0.1M); the value was nearly 10(4) for both Zn(II) and Cd(II) between pH 5 and 7 and pH 6 and 8, respectively.
引用
收藏
页码:379 / 385
页数:7
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