Sodium Phosphaethynolate as a Building Block for Heterocycles

被引:101
作者
Chen, Xiaodan [1 ]
Alidori, Simone [1 ]
Puschmann, Florian Frank [1 ]
Santiso-Quinones, Gustavo [1 ]
Benko, Zoltan [1 ]
Li, Zhongshu [1 ]
Becker, Gerd [2 ]
Gruetzmacher, Hans-Friedrich [3 ]
Gruetzmacher, Hansjoerg [1 ,4 ]
机构
[1] ETH, Dept Chem & Appl Biosci, CH-8093 Zurich, Switzerland
[2] Univ Stuttgart, Inst Anorg Chem, D-70550 Stuttgart, Germany
[3] Univ Bielefeld, Dept Chem, D-33501 Bielefeld, Germany
[4] Sun Yat Sen Univ, LIFM, Guangzhou 510275, Guangdong, Peoples R China
基金
瑞士国家科学基金会;
关键词
cycloaddition; multiple bonds; phosphinines; phosphorus heterocycles; sodium phosphaethynolate; COORDINATION CHEMISTRY; PHOSPHORUS-COMPOUNDS; CYCLOADDITION; AROMATICITY; LIGANDS;
D O I
10.1002/anie.201308220
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Phosphorus-containing heterocycles have evolved from laboratory curiosities to functional components, such as ligands in catalytically active metal complexes or molecular constituents in electronic devices. The straightforward synthesis of functionalized heterocycles on a larger scale remains a challenge. Herein, we report the use of the phosphaethynolate (OCP)(-) anion as a building block for various sterically unprotected and functionalized hydroxy substituted phosphorus heterocycles. Because the resulting heterocycles are themselves anions, they are building blocks in their own right and allow further facile functionalization. This property may be of interest in coordination chemistry and material science.
引用
收藏
页码:1641 / 1645
页数:5
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