Phase separation of binary nonadditive hard sphere fluid mixture confined in random porous media

I analyze the fluid-fluid phase separation of nonadditive hard sphere fluid mixture absorbed in random porous media. An equation of state is derived by using the perturbation theory to this complex system with quenched disorders. The results of this theory are in good agreement with those obtained from semi-grand canonical ensemble Monte Carlo simulations. The contact value of the fluid-fluid radial distribution functions of the reference which is the key point of the perturbation process is derived as well, the comparison against Monte Carlo simulations shows that it has an excellent accuracy. (C) 2013 AIP Publishing LLC.