Flexibility of network materials and the Rigid Unit Mode model: a personal perspective

被引:34
作者
Dove, Martin T. [1 ,2 ,3 ]
机构
[1] Wuhan Univ Technol, Sch Sci, Dept Phys, 205 Luoshi Rd, Wuhan 430070, Hubei, Peoples R China
[2] Sichuan Univ, Coll Phys Sci & Technol, Chengdu 610065, Sichuan, Peoples R China
[3] Queen Mary Univ London, Sch Phys & Astron, Mile End Rd, London E1 4NS, England
来源
PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES | 2019年 / 377卷 / 2149期
关键词
network materials; framework materials; Rigid Unit Modes; phase transitions; NEGATIVE THERMAL-EXPANSION; DISPLACIVE PHASE-TRANSITION; REVERSE MONTE-CARLO; FLOPPY MODES; INCOMMENSURATE PHASE; TOTAL SCATTERING; QUARTZ; DYNAMICS; ORDER; CRISTOBALITE;
D O I
10.1098/rsta.2018.0222
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The Rigid Unit Mode model was initially developed to understand the origin of displacive phase transitions in network silicate structures. Here, we review the successes of the model, and consider how it might apply to a wider range of network structures. This article is part of the theme issue 'Mineralomimesis: natural and synthetic frameworks in science and technology'.
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页数:18
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