Mesoporous manganese phthalocyanine-based materials for electrochemical water oxidation via tailored templating

被引：13
作者：
Broicher, C. [1 ]
Artz, J. [1 ]
Palkovits, S. [1 ]
Antoni, H. [2 ]
Droegeler, M. [3 ]
Morales, D. M. [4 ]
Stampfer, C. [3 ]
Palkovits, R. [1 ]
机构：
[1] Rhein Westfal TH Aachen, Inst Tech & Makromol Chem, Worringerweg 2, D-52074 Aachen, Germany
[2] Ruhr Univ Bochum, Lab Ind Chem, D-44780 Bochum, Germany
[3] Rhein Westfal TH Aachen, Inst Phys A 2, D-52074 Aachen, Germany
[4] Ruhr Univ Bochum, Analyt Chem, CES, D-44780 Bochum, Germany
来源：
CATALYSIS SCIENCE & TECHNOLOGY | 2018年 / 8卷 / 06期
关键词：
OXYGEN EVOLUTION; OXIDE; GRAPHENE; ELECTROCATALYSTS; REDUCTION; CATALYST; NANOCOMPOSITES; FABRICATION; SILICA; SPINEL;
D O I：
10.1039/c7cy02484c
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Electrochemical water splitting using non-noble metals as catalysts is of increasing importance for the future energy sector. In particular, efficient catalysts for the demanding oxygen evolution reaction present a major challenge. As a contribution to this field, tailored mesoporous hard template materials based on manganese phthalocyanine were prepared. The preparation method proved to be crucial to achieve suitable physicochemical properties as a basis for high catalytic activity. The materials show overpotentials between 490 and 590 mV at 10 mA cm(-2) This can be mainly attributed to efficient graphitization, high Mn dispersion and tailored oxidation states.
引用
收藏
页码：1517 / 1521
页数：5
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共 43 条
  • [1] The Hydrogen Issue
    Armaroli, Nicola
    Balzani, Vincenzo
    [J]. CHEMSUSCHEM, 2011, 4 (01) : 21 - 36
  • [2] Electrochemical water splitting by layered and 3D cross-linked manganese oxides: correlating structural motifs and catalytic activity
    Bergmann, Arno
    Zaharieva, Ivelina
    Dau, Holger
    Strasser, Peter
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (09) : 2745 - 2755
  • [3] Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni
    Biesinger, Mark C.
    Payne, Brad P.
    Grosvenor, Andrew P.
    Lau, Leo W. M.
    Gerson, Andrea R.
    Smart, Roger St. C.
    [J]. APPLIED SURFACE SCIENCE, 2011, 257 (07) : 2717 - 2730
  • [4] Synthesis, characterization, and electrochemical properties of ordered mesoporous carbons containing nickel oxide nanoparticles using sucrose and nickel acetate in a silica template
    Cao, Yulin
    Cao, Jieming
    Zheng, Mingbo
    Liu, Jinsong
    Ji, Guangbin
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2007, 180 (02) : 792 - 798
  • [5] Hydrogen-Evolution Catalysts Based on Non-Noble Metal Nickel-Molybdenum Nitride Nanosheets
    Chen, Wei-Fu
    Sasaki, Kotaro
    Ma, Chao
    Frenkel, Anatoly I.
    Marinkovic, Nebojsa
    Muckerman, James T.
    Zhu, Yimei
    Adzic, Radoslav R.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (25) : 6131 - 6135
  • [6] The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis
    Dau, Holger
    Limberg, Christian
    Reier, Tobias
    Risch, Marcel
    Roggan, Stefan
    Strasser, Peter
    [J]. CHEMCATCHEM, 2010, 2 (07) : 724 - 761
  • [7] Tuning the electrocatalysts for oxygen evolution reaction
    Eftekhari, Ali
    [J]. MATERIALS TODAY ENERGY, 2017, 5 : 37 - 57
  • [8] Fabrication of Spirocyclic Phosphazene Epoxy-Based Nanocomposites with Graphene via Exfoliation of Graphite Platelets and Thermal Curing for Enhancement of Mechanical and Conductive Properties
    Feng, Hua
    Wang, Xiaodong
    Wu, Dezhen
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2013, 52 (30) : 10160 - 10171
  • [9] Synthesis-structure correlations of manganese-cobalt mixed metal oxide nanoparticles
    Gliech, Manuel
    Bergmann, Arno
    Spoeri, Camillo
    Strasser, Peter
    [J]. JOURNAL OF ENERGY CHEMISTRY, 2016, 25 (02) : 278 - 281
  • [10] In Situ X-ray Absorption Spectroscopy Investigation of a Bifunctional Manganese Oxide Catalyst with High Activity for Electrochemical Water Oxidation and Oxygen Reduction
    Gorlin, Yelena
    Lassalle-Kaiser, Benedikt
    Benck, Jesse D.
    Gul, Sheraz
    Webb, Samuel M.
    Yachandra, Vittal K.
    Yano, Junko
    Jaramillo, Thomas F.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (23) : 8525 - 8534
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