Valorization of Carbon Dioxide into Oxazolidinones by Reaction with Aziridines

被引：17
作者：
Lamb, Katie J. [1 ]
Ingram, Ian D., V [1 ]
North, Michael [1 ]
Sengoden, Mani [1 ]
机构：
[1] Univ York, Green Chem Ctr Excellence, Chem Dept, York YO10 5DD, N Yorkshire, England
来源：
CURRENT GREEN CHEMISTRY | 2019年 / 6卷 / 01期
关键词：
Carbon dioxide; oxazolidinones; aziridines; metal catalysis; organocatalysis; homogenous catalyst; CHEMICAL FIXATION; SELECTIVE SYNTHESIS; CATALYZED SYNTHESIS; RECYCLABLE CATALYST; EFFICIENT CATALYST; HIGHLY EFFICIENT; CO2; 5-ARYL-2-OXAZOLIDINONES; CYCLOADDITION; MILD;
D O I：
10.2174/2213346106666190321142328
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reduction of carbon dioxide has gained much attention due to increasing environmental concerns about global warming associated with carbon emissions from industrial effluents and public transport etc. In this regard, considerable attention has been devoted to the chemical conversion of carbon dioxide, and its incorporation into synthetic organic molecules under mild and "green" conditions. In recent years, significant effort has been dedicated to studying the fixation of carbon dioxide with aziridines to afford oxazolidinones, which is an environmental friendly and atom economical process. In this review, we discuss the efficiency of different catalytic systems, by comparing and analyzing each reaction parameter such as pressure, temperature, substrate scope and product selectivity.
引用
收藏
页码：32 / 43
页数：12
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