A RAPID AND SENSITIVE SPECTROPHOTOMETRIC METHOD FOR THE DETERMINATION OF HYDROGEN PEROXIDE BY USING A REDOX REACTION

被引:0
|
作者
Narayana, B. [1 ]
Sreekumar, N. V. [1 ]
Shetty, D. N. [1 ]
机构
[1] Mangalore Univ, Dept Postgrad Studies & Res Chem, Mangalagangothri 574199, Karnataka, India
来源
OXIDATION COMMUNICATIONS | 2013年 / 36卷 / 02期
关键词
hydrogen peroxide; spectrophotometry; potassium iodide; variamine blue; RAINWATER; WATER;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple, rapid and sensitive spectrophotometric method is described for the determination of hydrogen peroxide using variamine blue (VB) as a chromogenic reagent. The proposed method is based on the liberation of iodine in acidic medium equivalent to the amount of hydrogen peroxide present, which oxidises variamine blue to form a violet coloured species having an absorption maximum at 560 nm. Hydrogen peroxide is determined in the range 0.8 to 8.0 x 10(-4) M. The Beer law limits, precision and accuracy of the method are checked by the UV reference method. The method is successfully adopted for various rainwater samples.
引用
收藏
页码:415 / 421
页数:7
相关论文
共 50 条
  • [21] Sensitive Determination of Epinephrine Using Kinetic Spectrophotometric Method
    Ekhtesasi, Atefah
    Shishehbore, Masoud Reza
    ORIENTAL JOURNAL OF CHEMISTRY, 2016, 32 (01) : 467 - 472
  • [22] Determination of hydrogen peroxide using an oscillating reaction system
    Hu, Gang
    Hu, Lin
    Zhang, Zude
    CHEMIA ANALITYCZNA, 2008, 53 (01): : 141 - 151
  • [23] Selective and sensitive spectrophotometric determination of total vanadium with hydrogen peroxide and 4-(2-pyridylazo)-resorcinol
    He, XW
    Tubino, M
    Rossi, AV
    ANALYTICA CHIMICA ACTA, 1999, 389 (1-3) : 275 - 280
  • [24] Sensitive spectrophotometric determination of hydrogen peroxide in aqueous samples from advanced oxidation processes: Evaluation of possible interferences
    Rubio-Clemente, A.
    Cardona, A.
    Chica, E.
    Penuela, G. A.
    AFINIDAD, 2017, 74 (579) : 161 - 168
  • [25] Inhibitory spectrophotometric determination of microamounts of thiosulfate based on the oxidizing discoloration reaction between crystal violet and hydrogen peroxide
    Rao, ZM
    Huang, SP
    Zhang, SQ
    CHINESE JOURNAL OF ANALYTICAL CHEMISTRY, 2004, 32 (09) : 1193 - 1195
  • [26] Inhibitory spectrophotometric determination of microamounts of thiosulfate based on the oxidizing discoloration reaction between crystal violet and hydrogen peroxide
    Rao, ZM
    Huang, SP
    Zhang, SQ
    CHINESE JOURNAL OF ANALYTICAL CHEMISTRY, 2004, 32 (08) : 1090 - 1092
  • [27] Spectrophotometric determination of hydrogen peroxide with osmium(VIII) and m-carboxyphenylfluorone
    Hoshino, Mitsuru
    Kamino, Shinichiro
    Doi, Mitsunobu
    Takada, Shingo
    Mitani, Shota
    Yanagihara, Rika
    Asano, Mamiko
    Yamaguchi, Takako
    Fujita, Yoshikazu
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2014, 117 : 814 - 816
  • [28] Quantum dot-based FRET for sensitive determination of hydrogen peroxide and glucose using tyramide reaction
    Huang, Xiangyi
    Wang, Jinjie
    Liu, Heng
    Lan, Tao
    Ren, Jicun
    TALANTA, 2013, 106 : 79 - 84
  • [29] SPECTROPHOTOMETRIC DETERMINATION OF HYDROGEN-PEROXIDE WITH LEUCO PATENT BLUE VIOLET
    CLAPP, PA
    EVANS, DF
    ANALYTICA CHIMICA ACTA, 1991, 243 (02) : 217 - 220
  • [30] A SENSITIVE SPECTROPHOTOMETRIC METHOD FOR DETERMINATION OF DIOSMIN USING SODIUM NITROPRUSSIDE AS A CHROMOGENIC REAGENT
    Moldovan, Zenovia
    Aboul-Enein, Hassan Y.
    INSTRUMENTATION SCIENCE & TECHNOLOGY, 2011, 39 (02) : 135 - 148