Fabrication of Lignocellulose-Based Microreactors: Copper-Functionalized Bamboo for Continuous-Flow CuAAC Click Reactions

被引：31

作者：

Sa, Druval Santos de ^{[1
]}

Bustamante, Rodrigo de Andrade ^{[2
]}

Rodrigues Rocha, Carlos Eduardo ^{[2
]}

da Silva, Veronica Diniz ^{[1
]}

da Rocha Rodrigues, Elton Jorge ^{[1
]}

Buarque Mueller, Camilla Djenne ^{[1
]}

Ghavam, Khosrow ^{[3
]}

Massi, Alessandro ^{[4
]}

Pandoli, Omar Ginoble ^{[1
]}

机构：

[1] Pontificia Univ Catolica Rio de Janeiro, Dept Quim, Rua Marque de Sao Vincente 225, BR-22451900 Rio de Janeiro, Brazil

[2] Pontificia Univ Catolica Rio de Janeiro, Dept Engn Quim & Mat, Rua Marque de Sao Vincente 225, BR-22451900 Rio de Janeiro, Brazil

[3] Pontificia Univ Catolica Rio de Janeiro, Dept Engn Civil, Rua Marque de Sao Vincente 225, BR-22451900 Rio de Janeiro, Brazil

[4] Univ Ferrara, Dipartimento Sci Chim & Farmaceut, Via Luigi Borsari 46, I-44121 Ferrara, Italy

来源：

ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2019年 / 7卷 / 03期

关键词：

Bio-microfluidic device; Click-chemistry; Heterogeneous catalysis; Bamboo; Sustainable microfabrication; Fast prototyping; Biomaterials; METAL-IONS; TECHNOLOGY; CELLULOSE; CYCLOADDITIONS; NANOPARTICLES; EFFICIENT; DEVICES;

D O I：

10.1021/acssuschemeng.8b05273

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The fabrication of a new copper-functionalized lignocellulosic microreactor (Cu-L mu R) from bamboo culms is herein described together with its operation to perform a copper(I)-catalyzed 1,3-dipolar cycloaddition between azide and terminal alkyne (CuAAC). The bio-microfluidic device showed an easy prototyping and fast functionalization with copper ions. All reactions were carried out in flow regime with aqueous-methanol solvent and minimal leaching of copper, yielding a series of model 1,4-disubstitued triazole derivatives with good efficiency in a low-resource setting.

引用

页码：3267 / 3273

页数：13