A New 6-Connected Ni(II) Complex With 5-methylisophthalic Acid: Synthesis, Crystal Structure, and Properties

被引：0

作者：

Chang, Xin-Hong ^{[1
]}

Sun, Xiao-Yuan ^{[2
]}

机构：

[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang, Peoples R China

[2] Bijie Univ, Coll Chem & Chem Engn, Bijie, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2013年 / 43卷 / 03期

关键词：

1; 6-bis(1; 2; 4-triazol-1-yl)hexane; 5-methylisophthalic acid; crystal structure; Ni(II) complex; LIGAND;

D O I：

10.1080/15533174.2012.740721

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new Ni(II) metalorganic coordination polymer, {[Ni(mip) (1,6-bth)(H2O)]center dot H2O}n (1), (H2mip = 5-methylisophthalic acid, 1,6-bth = 1,6-bis(1,2,4-triazol-1-yl)hexane), was assembled under hydrothermal condition by the reactions of Ni(II) acetate with H2mip and 1,6-bth. Compound 1 was characterized by elemental analysis, IR spectroscopy, and X-ray single-crystal diffraction. The results reveal that compound 1 consists of mip anion-bridged 1D NiII chains that are linked by 1,6-bth into a 2D layer. In addition, the thermal stability of 1 was briefly investigated.

引用

页码：279 / 282

页数：4

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