Mechanical performance of LaCrO3 doped with strontium and cobalt for SOFC interconnect

被引:10
作者
Acchar, W. [1 ]
Sousa, C. R. C. [1 ]
Mello-Castanho, S. R. H.
机构
[1] Fed Univ Rio Grande Norte UFRN, Postgrad Program Sci & Mat Engn, BR-59072970 Natal, RN, Brazil
来源
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING | 2012年 / 550卷
关键词
Lanthanum chromite; Sintering; Strength; Hardness; OXIDE FUEL-CELLS; CHROMITE; POWDERS;
D O I
10.1016/j.msea.2012.04.026
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Doped lanthanum chromite was investigated as ceramic interconnect materials to be used in high-temperature solid oxide fuel cells (SOFCs). In this work, a La0.80Sr0.20Cr0.92Co0.08O3 powder produced by combustion synthesis was used to obtain dense specimens. Powders were uniaxially compacted under a load of 30 MPa and sintered at 1500 degrees C for 4 h in air. The sintered specimens were characterized in terms of crystalline phases, density and porosity, strength and hardness measurements, deformation behavior, fracture mode and microstructure aspects. The results have shown dense samples (6.09 g/cm(3)) with strength and hardness values of 62 MPa and 5.98 GPa, respectively. Surface micrograph indicates a mixture of inter- and transgranular fracture modes, a brittle deformation behavior and grain size around 3 mu m. (c) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:76 / 79
页数:4
相关论文
共 19 条
[1]   Low temperature sintering of La(Ca) CrO3 prepared by an autoignition process [J].
Chakraborty, A ;
Basu, RN ;
Maiti, HS .
MATERIALS LETTERS, 2000, 45 (3-4) :162-166
[2]   Lanthanum chromite-based materials for solid oxide fuel cell interconnects [J].
Fergus, JW .
SOLID STATE IONICS, 2004, 171 (1-2) :1-15
[3]   Preparation and characterization of ceramic interconnect La0.8Ca0.2Cr0.9M0.1O3-δ (M = Al, Co, Cu, Fe) for IT-SOFCs [J].
Fu, Yen-Pei ;
Wang, Hsin-Chao .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (01) :747-754
[4]   Mechanical aspects of ferro-elastic behavior and phase composition of La0.58Sr0.4Co0.2Fe0.8O3-δ [J].
Huang, B. X. ;
Malzbender, J. ;
Steinbrech, R. W. ;
Wessel, E. ;
Penkalla, H. J. ;
Singheiser, L. .
JOURNAL OF MEMBRANE SCIENCE, 2010, 349 (1-2) :183-188
[5]  
Maixer D.L., 2002, SOLID STATE IONICS, V146, P285
[6]   Advanced measurement techniques to characterize thermo-mechanical aspects of solid oxide fuel cells [J].
Malzbender, J. ;
Steinbrech, R. W. .
JOURNAL OF POWER SOURCES, 2007, 173 (01) :60-67
[7]   Mechanical properties of LaCoO3 based ceramics [J].
Orlovskaya, N ;
Kleveland, K ;
Grande, T ;
Einarsrud, MA .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2000, 20 (01) :51-56
[8]   Effect of glass contents on the electrical and sintering property of La0.8Ca0.2CrO3/glass composite interconnects for solid oxide fuel cells [J].
Pi, Seuk-Hoon ;
Lee, Seung-Bok ;
Song, Rak-Hyun ;
Lee, Jong-Won ;
Lim, Tak-Hyoung ;
Park, Seok-Joo ;
Shin, Dong-Ryul ;
Park, Chong-Ook .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (21) :13735-13740
[9]   Hydrothermal synthesis of perovskite strontium doped lanthanum chromite fine powders and its sintering [J].
Rendon-Angeles, J. C. ;
Yanagisawa, K. ;
Matamoros-Veloza, Z. ;
Pech-Canul, M. I. ;
Mendez-Nonell, J. ;
Diaz-de la Torre, S. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 504 (01) :251-256
[10]  
Sakai N, 2004, INT J APPL CERAM TEC, V1, P23