Bis[μ-3-ethyl-4-phenyl-5-(2-pyridyl)-4H-1,2,4-triazole]bis[dichloridocopper(II)]

被引：13

作者：

Wang, Zuoxiang ^{[1
]}

Liu, Chunyi ^{[1
]}

Zhang, Xiaoming ^{[1
]}

Gong, Xiaoning ^{[1
]}

机构：

[1] Southeast Univ, Ordered Matter Sci Res Ctr, Nanjing 210096, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

关键词：

MAGNETIC-PROPERTIES; SPIN-CROSSOVER; COMPLEXES;

D O I：

10.1107/S160053680804035X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The asymmetric unit of the title compound, [Cu(2)Cl(4)(C(15)H(14)N(4))(2)], contains two halves of two centrosymmetric dinuclear molecules, A and B. The conformations of the two crystallographically independent molecules are slightly different: in A, the Cu center dot center dot center dot Cu separation is 4.174 (9) angstrom and the dihedral angle between the triazole and phenyl rings is 74.23 (11)degrees; these values are 4.137 (9) angstrom and 68.58 (13)degrees, respectively, in B. In each molecule, the copper(II) ions have a distorted trigonal-bipyramidal coordination geometry with a CuCl(2)NN'N '' chromophore. The crystal packing exhibits weak intermolecular C-H center dot center dot center dot Cl interactions.

引用

页码：M22 / U320

页数：11

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