Performance characteristics of supercapacitor electrodes made of silicon carbide nanowires grown on carbon fabric

被引:85
作者
Gu, Lin [1 ]
Wang, Yewu [1 ]
Fang, Yanjun [1 ]
Lu, Ren [1 ]
Sha, Jian [1 ]
机构
[1] Zhejiang Univ, Dept Phys, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China
基金
中国国家自然科学基金;
关键词
Supercapacitor; Electrical double-layer capacitors; Silicon carbide nanowires; Carbon fabric; Electrode materials; Cycle stability; CORE-SHELL NANOWIRES; ELECTROCHEMICAL CAPACITORS; FIELD-EMISSION; ENERGY; TEMPERATURE; STORAGE; ARRAYS;
D O I
10.1016/j.jpowsour.2013.06.050
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper, we report the supercapacitor electrodes with excellent cycle stability, which are made of silicon carbide nanowires (SiC NWs) grown on flexible carbon fabric. A high areal capacitance of 23 mF cm(-2) is achieved at a scan rate of 50 mV s(-1) at room temperature and capacitances increase with the rise of the working temperature. Owing to the excellent thermal stability of SiC NWs and carbon fabric, no observable decrease of capacitance occurs at room temperature (20 degrees C) after 10(5) cycles, which satisfies the demands of the commercial applications. Further increasing the measurement temperature to 60 degrees C, 90% of the initial capacitance is still retained after 10(5) cycles. This study shows that silicon carbide nanowires on carbon fabric are a promising electrode material for high temperature and stable micro-supercapacitors. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:648 / 653
页数:6
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