Air-Stable Dy(III)-Macrocycle Enantiomers: From Chiral to Polar Space Group
被引:33
|
作者:
Zhu, Zhenhua
论文数: 0引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
Univ Chinese Acad Sci, Beijing 100049, Peoples R ChinaChinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
Zhu, Zhenhua
[1
,2
]
Zhao, Chen
论文数: 0引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
Univ Sci & Technol China, Hefei 230026, Peoples R ChinaChinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
Zhao, Chen
[1
,3
]
Zhou, Quan
论文数: 0引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
Univ Sci & Technol China, Hefei 230026, Peoples R ChinaChinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
Zhou, Quan
[1
,3
]
Liu, Shuting
论文数: 0引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
Univ Sci & Technol China, Hefei 230026, Peoples R ChinaChinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
Liu, Shuting
[1
,3
]
Li, Xiao-Lei
论文数: 0引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R ChinaChinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
Li, Xiao-Lei
[1
]
Mansikkamaki, Akseli
论文数: 0引用数: 0
h-index: 0
机构:
Univ Oulu, NMR Res Unit, FI-90014 Oulu, FinlandChinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
Mansikkamaki, Akseli
[4
]
Tang, Jinkui
论文数: 0引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
Univ Sci & Technol China, Hefei 230026, Peoples R ChinaChinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
Tang, Jinkui
[1
,3
]
机构:
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Univ Sci & Technol China, Hefei 230026, Peoples R China
[4] Univ Oulu, NMR Res Unit, FI-90014 Oulu, Finland
来源:
CCS CHEMISTRY
|
2022年
/
4卷
/
12期
基金:
芬兰科学院;
中国国家自然科学基金;
关键词:
Dy(III)-macrocycle enantiomers;
chiral polar space group;
single-molecule magnets;
MOLECULE MAGNET BEHAVIOR;
ANO BASIS-SETS;
ROOM-TEMPERATURE;
MAGNETIZATION;
COMPLEXES;
ORIGIN;
ATOMS;
STATE;
D O I:
10.31635/ccschem.022.202101604
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Magnetoelectric (ME) multiferroic materials have unique advantages in low-power and high-density information storage, because they can simultaneously display ferroelectricity and ferromagnetism. However, research on how to construct air-stable high-performance ME single-molecule magnets (SMMs) is nonexistent. Herein, by introducing homochirality while reducing molecular symmetry, two double-decker Dy(III) enantiomers adopting the polar space group P2(1) and exhibiting excellent thermal stability were obtained. They displayed zero field SMM behavior with an anisotropy barrier (U-eff) of ca. 100 cm(-1). This work establishes a rational chemical design strategy for crystallizing SMMs in polar space groups and elucidates the direction for future research, that is, engineering small-size high-performance SMMs. [GRAPHICS] .
机构:
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun,130022, ChinaState Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun,130022, China
Zhu, Zhenhua
Paul, Sagar
论文数: 0引用数: 0
h-index: 0
机构:
Physikalisches Institut, Karlsruhe Institute of Technology (KIT), Engesserstraße 15, Karlsruhe,D-76131, GermanyState Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun,130022, China
Paul, Sagar
Zhao, Chen
论文数: 0引用数: 0
h-index: 0
机构:
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun,130022, ChinaState Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun,130022, China
Zhao, Chen
Wu, Jianfeng
论文数: 0引用数: 0
h-index: 0
机构:
School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi’an,710072, ChinaState Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun,130022, China
Wu, Jianfeng
Ying, Xu
论文数: 0引用数: 0
h-index: 0
机构:
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun,130022, ChinaState Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun,130022, China
Ying, Xu
论文数: 引用数:
h-index:
机构:
Ungur, Liviu
Wernsdorfer, Wolfgang
论文数: 0引用数: 0
h-index: 0
机构:
Physikalisches Institut, Karlsruhe Institute of Technology (KIT), Engesserstraße 15, Karlsruhe,D-76131, GermanyState Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun,130022, China
Wernsdorfer, Wolfgang
Meyer, Franc
论文数: 0引用数: 0
h-index: 0
机构:
Institut für Anorganische Chemie, Universität Göttingen, Tammannstraße 4, Göttingen,D-37077, GermanyState Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun,130022, China
Meyer, Franc
Tang, Jinkui
论文数: 0引用数: 0
h-index: 0
机构:
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun,130022, China
School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei,230026, ChinaState Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun,130022, China