Regeneration mechanisms of high-lithium content zirconates as CO2 capture sorbents: experimental measurements and theoretical investigations

被引：19

作者：

Duan, Yuhua ^{[1
]}

Lekse, Jonathan ^{[1
,2
]}

机构：

[1] US DOE, Natl Energy Technol Lab, Pittsburgh, PA 15236 USA

[2] URS Corp, South Pk, PA 15219 USA

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2015年 / 17卷 / 35期

关键词：

CARBON-DIOXIDE SORPTION; TEMPERATURE; ABSORPTION; LI4SIO4; CHEMISORPTION; SEQUESTRATION; TECHNOLOGY; SILICATES; STORAGE;

D O I：

10.1039/c5cp03968a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

By combining TGA and XRD measurements with theoretical calculations of the capture of CO2 by lithium-rich zirconates (Li8ZrO6 and Li6Zr2O7), it has been demonstrated that the primary regeneration product during absorption/desorption cycling is in the form of Li2ZrO3. During absorption/desorption cycles, lithium-rich zirconates will be consumed and will not be regenerated. This result indicates that among known lithium zirconates, Li2ZrO3 is the best sorbent for CO2 capture.

引用

页码：22543 / 22547

页数：5

共 44 条

[1] Carbon capture and storage update [J].

Boot-Handford, M. E. ;

Abanades, J. C. ;

Anthony, E. J. ;

Blunt, M. J. ;

Brandani, S. ;

Mac Dowell, N. ;

Fernandez, J. R. ;

Ferrari, M. -C. ;

Gross, R. ;

Hallett, J. P. ;

Haszeldine, R. S. ;

Heptonstall, P. ;

Lyngfelt, A. ;

Makuch, Z. ;

Mangano, E. ;

Porter, R. T. J. ;

Pourkashanian, M. ;

Rochelle, G. T. ;

Shah, N. ;

Yao, J. G. ;

Fennell, P. S. .

ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (01) :130-189

[2]

Chen C, 2014, KOREAN J CHEM ENG, V31, P1919

[3]

Duan Y., 2014, SCIENCEJET, V3, P56

[4]

Duan Y., 2012, Int. J. Clean Coal Energy, V1, P1, DOI [10.4236/ijcce.2012.11001, DOI 10.4236/IJCCE.2012.11001]

[5] Electronic Structure, Phonon Dynamical Properties, and Capture Capability of Na2-xMxZrO3 (M=Li,K): Density-Functional Calculations and Experimental Validations [J].

Duan, Yuhua ;

Lekse, Jonathan ;

Wang, Xianfeng ;

Li, Bingyun ;

Alcántar-Vázquez, Brenda ;

Pfeiffer, Heriberto ;

Halley, J. W. .

PHYSICAL REVIEW APPLIED, 2015, 3 (04)

[6] CO2 capture properties of lithium silicates with different ratios of Li2O/SiO2: an ab initio thermodynamic and experimental approach [J].

Duan, Yuhua ;

Pfeiffer, Heriberto ;

Li, Bingyun ;

Romero-Ibarra, Issis C. ;

Sorescu, Dan C. ;

Luebke, David R. ;

Halley, J. Woods .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (32) :13538-13558

[7] Structural and electronic properties of Li8ZrO6 and its CO2 capture capabilities: an ab initio thermodynamic approach [J].

Duan, Yuhua .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (24) :9752-9760

[8] A first-principles density functional theory study of the electronic structural and thermodynamic properties of M2ZrO3 and M2CO3 (M=Na, K) and their capabilities for CO2 capture [J].

Duan, Yuhua .

JOURNAL OF RENEWABLE AND SUSTAINABLE ENERGY, 2012, 4 (01)

[9] Density functional theory study of the structural, electronic, lattice dynamical, and thermodynamic properties of Li4SiO4 and its capability for CO2 capture [J].

Duan, Yuhua ;

Parlinski, K. .

PHYSICAL REVIEW B, 2011, 84 (10)

[10] Electronic structural and electrochemical properties of lithium zirconates and their capabilities of CO2 capture: A first-principles density-functional theory and phonon dynamics approach [J].

Duan, Yuhua .

JOURNAL OF RENEWABLE AND SUSTAINABLE ENERGY, 2011, 3 (01)

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