Photodimerization and complexation dynamics of coumarins in the presence of cucurbit[8]urils

被引：38

作者：

Barooah, Nilotpal ^{[1
]}

Pemberton, Barry C. ^{[1
]}

Johnson, Alexander C. ^{[1
]}

Sivaguru, J. ^{[1
]}

机构：

[1] N Dakota State Univ, Dept Chem & Mol Biol, Fargo, ND 58105 USA

来源：

PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES | 2008年 / 7卷 / 12期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1039/b814230k

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Coumarin derivatives with non-polar substituents at the 6 or 7 position undergoes photodimerization in the presence of CB[ 8] in water to give the syn dimer as the major product. It is postulated that these neutral coumarins form dynamic complexes in the presence of CB[ 8] and the product selectivity is reflective of the type of complex, available volume in the CB[ 8] cavity and relative rate of photodimerization inside and outside the CB[ 8] cavity.

引用

页码：1473 / 1479

页数：7

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