Pressure-induced magnetic transition and sound velocities of Fe3C:: Implications for carbon in the Earth's inner core

被引:69
作者
Gao, Lili [1 ,2 ]
Chen, Bin [1 ]
Wang, Jingyun [1 ]
Alp, Esen E. [2 ]
Zhao, Jiyong [2 ]
Lerche, Michael [2 ,4 ]
Sturhahn, Wolfgang [2 ]
Scott, Henry P. [3 ]
Huang, Fang [1 ]
Ding, Yang [4 ,5 ]
Sinogeikin, Stanislav V. [5 ]
Lundstrom, Craig C. [1 ]
Bass, Jay D. [1 ]
Li, Jie [1 ]
机构
[1] Univ Illinois, Dept Geol, Urbana, IL 61801 USA
[2] Argonne Natl Lab, Adv Photon Source, Argonne, IL 60439 USA
[3] Indiana Univ, Dept Phys & Astron, South Bend, IN 46634 USA
[4] Carnegie Inst Washington, High Pressure Synerget Consortium, Argonne, IL USA
[5] Carnegie Inst Washington, HPCAT & Geophys Lab, Argonne, IL USA
关键词
D O I
10.1029/2008GL034817
中图分类号
P [天文学、地球科学];
学科分类号
07 ;
摘要
We have carried out nuclear resonant scattering measurements on (57)Fe-enriched Fe(3)C between 1 bar and 50 GPa at 300 K. Synchrotron Mossbauer spectra reveal a pressure-induced magnetic transition in Fe3C between 4.3 and 6.5 GPa. On the basis of our nuclear resonant inelastic X-ray scattering spectra and existing equation-of-state data, we have derived the compressional wave velocity V(P) and shear wave velocity VS for the high-pressure nonmagnetic phase, which can be expressed as functions of density (rho): V(P)(km/s) = -3.99 + 1.29 rho(g/cm(3)) and V(S)(km/s) = 1.45 + 0.24 rho(g/cm(3)). The addition of carbon to iron-nickel alloy brings density, V(P) and V(S) closer to seismic observations, supporting carbon as a principal light element in the Earth's inner core.
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页数:5
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