Femtosecond dynamics in single wall carbon nanotube/poly(3-hexylthiophene) composites

被引:14
作者
Lioudakis, Emmanouil [1 ]
Othonos, Andreas [1 ]
Alexandrou, Ioannis [2 ]
机构
[1] Univ Cyprus, Res Ctr Ultrafast Sci, Dept Phys, CY-1678 Nicosia, Cyprus
[2] Univ Liverpool, Liverpool L69 3GJ, Merseyside, England
来源
NANOSCALE RESEARCH LETTERS | 2008年 / 3卷 / 08期
关键词
ultrafast spectroscopy; single wall carbon nanotubes; exciton dissociation;
D O I
10.1007/s11671-008-9149-x
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Femtosecond transient absorption measurements on single wall carbon nanotube/poly(3-hexylthiophene) composites are used to investigate the relaxation dynamics of this blended material. The influence of the addition of nanotubes in polymer matrix on the ultrashort relaxation dynamics is examined in detail. The introduction of nanotube/polymer heterojunctions enhances the exciton dissociation and quenches the radiative recombination of composites. The relaxation dynamics of these composites are compared with the fullerene derivative-polymer composites with the same matrix. These results provide explanation to the observed photovoltaic performance of two types of composites.
引用
收藏
页码:278 / 283
页数:6
相关论文
共 27 条
[1]   Carbon nanotubes - the route toward applications [J].
Baughman, RH ;
Zakhidov, AA ;
de Heer, WA .
SCIENCE, 2002, 297 (5582) :787-792
[2]   Carbon nanotube composites for thermal management [J].
Biercuk, MJ ;
Llaguno, MC ;
Radosavljevic, M ;
Hyun, JK ;
Johnson, AT ;
Fischer, JE .
APPLIED PHYSICS LETTERS, 2002, 80 (15) :2767-2769
[3]   Excitons in carbon nanotubes:: An ab initio symmetry-based approach -: art. no. 196401 [J].
Chang, E ;
Bussi, G ;
Ruini, A ;
Molinari, E .
PHYSICAL REVIEW LETTERS, 2004, 92 (19) :196401-1
[4]   FULLERENES - DOWN THE STRAIGHT AND NARROW [J].
DRESSELHAUS, MS .
NATURE, 1992, 358 (6383) :195-196
[5]   Inverse relation between photocurrent and absorption layer thickness in polymer solar cells [J].
Hoppe, Harald ;
Shokhovets, Sviatoslav ;
Gobsch, Gerhard .
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS, 2007, 1 (01) :R40-R42
[6]  
IJIMA S, 1991, NATURE, V354, P56
[7]   Effect of intertube coupling on the electronic structure of carbon nanotube ropes [J].
Kwon, YK ;
Saito, S ;
Tomanek, D .
PHYSICAL REVIEW B, 1998, 58 (20) :13314-13317
[8]   High open-circuit voltage photovoltaic devices from carbon-nanotube-polymer composites [J].
Kymakis, E ;
Alexandrou, I ;
Amaratunga, GAJ .
JOURNAL OF APPLIED PHYSICS, 2003, 93 (03) :1764-1768
[9]   Single-walled carbon nanotube-polymer composites: electrical, optical and structural investigation [J].
Kymakis, E ;
Alexandou, I ;
Amaratunga, GAJ .
SYNTHETIC METALS, 2002, 127 (1-3) :59-62
[10]   Electrical properties of single-wall carbon nanotube-polymer composite films [J].
Kymakis, Emmanuel ;
Amaratunga, Gehan A. J. .
JOURNAL OF APPLIED PHYSICS, 2006, 99 (08)