Degradation of methylene blue via Co-TiO2 nano powders modified by meso-tetra(carboxyphenyl)porphyrin

被引:40
作者
Rahimi, Rahmatollah [1 ]
Fard, Elham Honarvar [1 ]
Saadati, Sara [1 ]
Rabbani, Mahboubeh [1 ]
机构
[1] Iran Univ Sci & Technol, Dept Chem, Tehran, Iran
关键词
Photocatalytic activity; Porphyrin/cobalt doped TiO2; Methylene blue degradation; SOL-GEL PREPARATION; PHOTOCATALYTIC DEGRADATION; THIN-FILMS; TIO2; PERFORMANCE; FE-TIO2; DYE;
D O I
10.1007/s10971-012-2733-7
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
TiO2 photocatalylysts as an environmental cleaning factor has drawn considerable attention due to the global increase in the level of environmental pollutions. Studies on the development of new TiO2 materials wherein its photocatalytic activity can be activated by visible light will be valuable for field application. In this study, porphyrins/Co-doped TiO2 were prepared by sol-gel method. The nanopowders were characterized by means of X-ray diffraction, energy dispersive X-ray spectroscopy, IR spectroscopy and transmission electron microscopy (SEM). In addition, the photocatalytic degrading efficiency of porphyrins/Co-doped TiO2 complexes on the methylene blue decomposition under irradiation with visible light is evaluated.
引用
收藏
页码:351 / 357
页数:7
相关论文
共 25 条
[1]   ON PREPARATION OF METALLOPORPHYRINS [J].
ADLER, AD ;
LONGO, FR ;
KAMPAS, F ;
KIM, J .
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1970, 32 (07) :2443-&
[2]   PHOTOCATALYTIC REDUCTION OF CO2 WITH H2O ON VARIOUS TITANIUM-OXIDE CATALYSTS [J].
ANPO, M ;
YAMASHITA, H ;
ICHIHASHI, Y ;
EHARA, S .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1995, 396 (1-2) :21-26
[3]   Effect of tantalum addition on anatase phase stability and photoactivity of aqueous sol-gel derived mesoporous titania [J].
Baiju, K. V. ;
Shajesh, P. ;
Wunderlich, W. ;
Mukundan, P. ;
Kumar, S. Rajesh ;
Warrier, K. G. K. .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 276 (1-2) :41-46
[4]   Improving visible-light photocatalytic activity of N-doped TiO2 nanoparticles via sensitization by Zn porphyrin [J].
Chen, Daimei ;
Yang, Dong ;
Geng, Jiaqing ;
Zhu, Juhong ;
Jiang, Zhongyi .
APPLIED SURFACE SCIENCE, 2008, 255 (05) :2879-2884
[5]   Sol-Gel Preparation and Characterization of Co/TiO2 Nanoparticles: Application to the Degradation of Methyl Orange [J].
Hamadanian, M. ;
Reisi-Vanani, A. ;
Majedi, A. .
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2010, 7 :S52-S58
[6]   Synthesis, characterization and effect of calcination temperature on phase transformation and photocatalytic activity of Cu,S-codoped TiO2 nanoparticles [J].
Hamadanian, M. ;
Reisi-Vanani, A. ;
Majedi, A. .
APPLIED SURFACE SCIENCE, 2010, 256 (06) :1837-1844
[7]   High sensitivity and fast response hydrogen sensors based on electrochemically etched porous titania thin films [J].
Hazra, SK ;
Basu, S .
SENSORS AND ACTUATORS B-CHEMICAL, 2006, 115 (01) :403-411
[8]   ENVIRONMENTAL APPLICATIONS OF SEMICONDUCTOR PHOTOCATALYSIS [J].
HOFFMANN, MR ;
MARTIN, ST ;
CHOI, WY ;
BAHNEMANN, DW .
CHEMICAL REVIEWS, 1995, 95 (01) :69-96
[9]   Facile fabrication of mesoporous TiO2 electrodes for dye solar cells:: chemical modification and repetitive coating [J].
Ito, S ;
Kitamura, T ;
Wada, Y ;
Yanagida, S .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2003, 76 (01) :3-13
[10]   Visible light active platinum-ion-doped TiO2 photocatalyst [J].
Kim, S ;
Hwang, SJ ;
Choi, WY .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (51) :24260-24267