Cu(0) nanoparticle-decorated functionalized reduced graphene oxide sheets as artificial peroxidase enzymes: application for colorimetric detection of Cr(VI) ions

被引：23

作者：

Borthakur, Priyakshree ^{[1
,2
]}

Boruah, Purna K. ^{[1
,2
]}

Das, Manash R. ^{[1
,2
]}

Szunerits, Sabine ^{[3
]}

Boukherroub, Rabah ^{[3
]}

机构：

[1] North East Inst Sci & Technol, Mat Sci & Technol Div, Adv Mat Grp, CSIR, Jorhat 785006, Assam, India

[2] NEIST Campus, Acad Sci & Innovat Res AcSIR, CSIR, Jorhat, Assam, India

[3] Univ Lille, Univ Valenciennes, CNRS, UMR 8520,Cent Lille,ISEN,IEMN, F-59000 Lille, France

来源：

NEW JOURNAL OF CHEMISTRY | 2019年 / 43卷 / 03期

关键词：

CLICK-CHEMISTRY; GREEN SYNTHESIS; NANOCOMPOSITES; NANOSHEETS; REDUCTION; MOLECULES;

D O I：

10.1039/c8nj05363d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Graphene oxide (GO) sheets were functionalized by a "click" chemistry approach using azide modified GO and alkynyl-terminated D(+)-glucose precursors to produce glucose terminated hydrophilic GO surfaces. This hydrophilic functionalized GO surface was utilized for the decoration of Cu(0) nanoparticles for sensitive colorimetric detection of Cr(VI) ions, which has not been explored to date. The nanocomposite exhibited excellent peroxidase mimic activity towards the colourless chromogenic substance, 3,3',5,5'-tetramethylbenzidine (TMB), to yield a blue coloured substance 3,3',5,5'-tetramethylbenzidinediimmine (TMBDI). In an acidic medium, Cr(VI) can decompose H2O2 to molecular O-2 and H2O. Both O-2 and H2O can form hydroxyl radicals ((OH)-O-center dot) by combining with the electron of the peroxidase substrate, resulting in enhanced TMB oxidation in the presence of Cr(VI). This colorimetric method was highly selective towards Cr(VI) ions with a limit of detection (LOD) of 67.13 nM.

引用

页码：1404 / 1414

页数：11

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